Ultrafast elementary photochemical processes of organic molecules in liquid solution

T Kumpulainen, B Lang, A Rosspeintner… - Chemical …, 2017 - ACS Publications
Ultrafast photochemical reactions in liquids occur on similar or shorter time scales compared
to the equilibration of the optically populated excited state. This equilibration involves the …

Structure and dynamics of monohydroxy alcohols—Milestones towards their microscopic understanding, 100 years after Debye

R Böhmer, C Gainaru, R Richert - Physics Reports, 2014 - Elsevier
In 1913 Debye devised a relaxation model for application to the dielectric properties of water
and alcohols. These hydrogen-bonded liquids continue to be studied extensively because …

Terahertz spectroscopy

MC Beard, GM Turner… - The Journal of Physical …, 2002 - ACS Publications
Terahertz spectroscopy emerged about 13 years ago with the demonstration that nearly
single-cycle pulses of far-infrared radiation could be generated, propagated through free …

A natural product that lowers cholesterol as an antagonist ligand for FXR

NL Urizar, AB Liverman, DNT Dodds, FV Silva… - Science, 2002 - science.org
Extracts of the resin of the guggul tree (Commiphora mukul) lower LDL (low-density
lipoprotein) cholesterol levels in humans. The plant sterol guggulsterone [4, 17 (20) …

Ultrafast electron transfer at the molecule-semiconductor nanoparticle interface

NA Anderson, T Lian - Annu. Rev. Phys. Chem., 2005 - annualreviews.org
▪ Abstract Electron transfer across the molecule-semiconductor interface is a fundamental
process that is relevant to many applications of nanoparticles, such as dye-sensitized solar …

Optical Kerr effect in liquids

PP Ho, RR Alfano - Physical Review A, 1979 - APS
An experimental study was undertaken to measure the optical Kerr effect (OKE) in liquids
induced by picosecond laser pulses. The effects of different parameters on the dynamics of …

Morphology and intermolecular dynamics of 1-alkyl-3-methylimidazolium bis {(trifluoromethane) sulfonyl} amide ionic liquids: structural and dynamic evidence of …

O Russina, A Triolo, L Gontrani… - Journal of Physics …, 2009 - iopscience.iop.org
Here we report on the structural and dynamical properties of a series of room temperature
ionic liquids, namely 1-alkyl-3-methylimidazolium bis {(trifluoromethane) sulfonyl} amide ([C …

Relation between dielectric and low-frequency Raman spectra of hydrogen-bond liquids

T Fukasawa, T Sato, J Watanabe, Y Hama, W Kunz… - Physical review …, 2005 - APS
We analyzed the complex dielectric and Raman spectra of hydrogen-bond liquids in the
microwave to terahertz frequency range. As for water and methanol, the high-frequency …

Probing protein electrostatics with a synthetic fluorescent amino acid

BE Cohen, TB McAnaney, ES Park, YN Jan, SG Boxer… - Science, 2002 - science.org
Electrostatics affect virtually all aspects of protein structure and activity and are particularly
important in proteins whose primary function is to stabilize charge. Here we introduce a …

Chemical exchange 2D IR of hydrogen-bond making and breaking

YS Kim, RM Hochstrasser - Proceedings of the National …, 2005 - National Acad Sciences
The involvement of chemical exchange in 2D IR heterodyne echo spectroscopy is
characterized through the hydrogen-bond exchange between CH3OH and the CN of …