Recent advances on high-nuclear polyoxometalate clusters

JC Liu, JW Zhao, C Streb, YF Song - Coordination Chemistry Reviews, 2022 - Elsevier
The design and construction of high-nuclear polyoxometalate (POM) clusters remain a
severe challenge, but attract significant interest on account of their impressive structural …

Recent advances in lanthanide-coordinated polyoxometalates: from structural overview to functional materials

CM Granadeiro, D Julião, SO Ribeiro… - Coordination Chemistry …, 2023 - Elsevier
Lanthanopolyoxometalates (LnPOMs), obtained through the coordination of
polyoxometalates (POMs) and lanthanide ions (Ln), have received extraordinary interest of …

Four‐Shell Polyoxometalates Featuring High‐Nuclearity Ln26 Clusters: Structural Transformations of Nanoclusters into Frameworks Triggered by Transition‐Metal …

Z Li, XX Li, T Yang, ZW Cai, ST Zheng - Angewandte Chemie, 2017 - Wiley Online Library
A series of polyoxometalates (POMs) that incorporate the highest‐nuclearity Ln clusters that
have been observed in such structures to date (Ln26, Ln= La and Ce) are described, which …

Hexameric to trimeric lanthanide-included selenotungstates and their 2D honeycomb organic–inorganic hybrid films used for detecting ochratoxin A

L Liu, J Jiang, G Liu, X Jia, J Zhao… - ACS Applied Materials …, 2021 - ACS Publications
Two types of organic–inorganic hybrid structure-related lanthanide (Ln)-included
selenotungstates (Ln-SeTs)[H2N (CH3) 2] 11Na7 [Ce4 (H2PTCA) 2 (H2O) 12 (HICA)] 2 …

A giant Ce-containing poly (tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant

C Lian, SH Zhao, HL Li, X Cao - Chinese Chemical Letters, 2024 - Elsevier
A novel Ce-containing poly (tungstobismuthate) Cs 18 Na 8 H 20 [Ce 3 (H 2 O) 10 W 8 Bi 4
O 28 (B-α-BiW 9 O 33) 4] 2· 64H 2 O (1) has been synthesized by a facile one-pot self …

Dual-heteroatom-templated lanthanoid-inserted heteropolyoxotungstates simultaneously comprising Dawson and Keggin subunits and their composite film applied for …

S Xie, D Wang, Z Wang, J Liu, L Chen… - Inorganic Chemistry …, 2022 - pubs.rsc.org
Two PIII–SbIII-heteroatom-templated lanthanoid (Ln)-inserted polyoxotungstates [H2N
(CH3) 2] 10NaH9 [Ln4 (H2O) 14W7O15 (H2MA) 4][SbIIIW9O33] 2 [HPIIISbIIIW15O54] 2 …

Self-sorting of heteroanions in the assembly of cross-shaped polyoxometalate clusters

Q Zheng, L Vilà-Nadal, Z Lang, JJ Chen… - Journal of the …, 2018 - ACS Publications
Heteroanion (HA) moieties have a key role in templating of heteropolyoxometalate (HPA)
architectures, but clusters templated by two different templates are rarely reported. Herein …

Lanthanide-incorporated polyoxometalates assembled from mixed-heteroatom-oriented three-layered cage clusters

T Gong, J Jiang, S Yang, J Liu, L Chen… - Inorganic …, 2022 - ACS Publications
Discovering innovative metal-oxo cluster materials with uncommon building blocks and
exploiting their application potentiality are fairly challengeable. Here, we provide a novel …

Two unusual nanosized Nd 3+-substituted selenotungstate aggregates simultaneously comprising lacunary Keggin and Dawson polyoxotungstate segments

H Li, C Lian, L Chen, J Zhao, GY Yang - Nanoscale, 2020 - pubs.rsc.org
Two unique nanosized Nd3+-substituted selenotungstates Na9K8 {[W3Nd2 (H2O) 3 (NO3)
O6](B-α-SeW9O33) 2 (α-Se2W14O52)}· 35H2O (1) and [H2N (CH3) 2] 7H9Na4 {[W2Nd2 …

Organic–inorganic hybrid cerium-encapsulated selenotungstate including three building blocks and its electrochemical detection of dopamine and paracetamol

J Jiang, L Liu, G Liu, D Wang, Y Zhang… - Inorganic …, 2020 - ACS Publications
A novel organic–inorganic hybrid cerium-encapsulated selenotungstate comprising three
polyoxotungstate building units Na16H6 {[Ce3W4O10 (H2O) 9 (CH3COO) 3] 2 …