The area of direct asymmetric functionalization of inert C–H bonds has attracted
considerable attention in recent years. To realize this type of challenging but promising …

Replacement of the furanosyl oxygen with a methylene unit in the ribose sugar in
nucleosides 1 and nucleotides 2 prompted the rise of a new nucleoside class with very …

Axial chirality features prominently in molecules of biological interest as well as chiral
catalyst designs, and atropisomeric 2, 2′-biphenols are particularly prevalent …

Atropisomerically enriched biaryl frameworks are ubiquitous in many fields of chemistry.
Enantioselective aryl–aryl cross-coupling provides the most straightforward entry to …

Biaryl compounds with axial chirality are very common in synthetic chemistry, especially in
catalysis. Axially chiral biaryls are important due to their biological activities and extensive …

Atropisomeric biaryl motifs are ubiquitous in chiral catalysts and ligands. Numerous efficient
strategies have been developed for the synthesis of axially chiral biaryls. In contrast, the …

The first phosphoric acid catalyzed direct arylation of 2‐naphthylamines with iminoquinones
for the atroposelective synthesis of axially chiral biaryl amino alcohols has been developed …

A novel type of chiral redox disulfonate iron complex for asymmetric catalysis is reported.
The [Fe ((R a)-BINSate)]+(BINSate= 1, 1′-binaphthalene-2, 2′-disulfonate) complex …

Axially chiral biaryl amino-alcohols play a pivotal role in organic synthesis and drug
discovery. However, only a very few enantioselective methods have been reported to …

Functionalization of arenes represents the most efficient approach for constructing a core
backbone of important aryl compounds. Compared with the well-developed electrophilic …