Looking into the future of hybrid glasses

TD Bennett, S Horike, JC Mauro, MM Smedskjaer… - Nature Chemistry, 2024 - nature.com
Glasses are typically formed by melt-quenching, that is, cooling of a liquid on a timescale
fast enough to avoid ordering to a crystalline state, and formerly thought to comprise three …

Synthetic and analytical considerations for the preparation of amorphous metal–organic frameworks

EV Shaw, AM Chester, GP Robertson… - Chemical …, 2024 - pubs.rsc.org
Metal–organic frameworks (MOFs) are hybrid porous materials presenting several tuneable
properties, allowing them to be utilised for a wide range of applications. To date, focus has …

Engineering a hierarchical carbon supported magnetite nanoparticles composite from metal organic framework and graphene oxide for lithium-ion storage

R Jia, R Zhang, L Yu, X Kong, S Bao, M Tu… - Journal of Colloid and …, 2023 - Elsevier
Fe based metal organic framework (MOF) materials are being extensively investigated as a
precursor sample for engineering carbon supported iron containing nanoparticles …

Modeling the Effect of Defects and Disorder in Amorphous Metal–Organic Frameworks

I Bechis, AF Sapnik, A Tarzia, EH Wolpert… - Chemistry of …, 2022 - ACS Publications
Amorphous metal–organic frameworks (a MOFs) are a class of disordered framework
materials with a defined local order given by the connectivity between inorganic nodes and …

Mapping nanocrystalline disorder within an amorphous metal–organic framework

AF Sapnik, C Sun, JEM Laulainen… - Communications …, 2023 - nature.com
Intentionally disordered metal–organic frameworks (MOFs) display rich functional behaviour.
However, the characterisation of their atomic structures remains incredibly challenging. X …

Beyond the selectivity-capacity trade-off: ultrathin carbon nanoplates with easily accessible ultramicropores for high-efficiency propylene/propane separation

S Xu, WC Li, C Wang, R Liu, GP Hao, AH Lu - Nano Letters, 2022 - ACS Publications
Rapid and highly efficient C3H6/C3H8 separation over porous carbons is seriously hindered
by the trade-off effect between adsorption capacity and selectivity. Here, we report a new …

[HTML][HTML] Entropy driven disorder–order transition of a metal–organic framework with frustrated flexibility

R Pallach, JB Weiß, K Vollmari, S Henke - APL Materials, 2023 - pubs.aip.org
Flexible metal–organic frameworks (MOFs), showing a reversible phase change behavior in
response to guest adsorption or temperature, provide unique opportunities for molecular …

Rapid Aqueous Medium Organization of Trimesate Metal–Organic Frameworks of Cu, Fe: Exploring Suitability in Gas Separation

S Dalakoti, N Singh, HN Wamba… - ACS Applied …, 2023 - ACS Publications
There has been a steady growth in research on porous materials such as metal–organic
frameworks (MOFs) for their various applications. A significant drawback of conventional …

[HTML][HTML] Magnetic framework composites via continuous flow syntheses for CO2 capture

JL Woodliffe, J Molinar-Díaz, B Holland… - Chemical Engineering …, 2025 - Elsevier
Magnetic framework composites (MFCs) are a novel class of materials containing magnetic
nanoparticles with metal–organic frameworks (MOFs). They have demonstrated exciting …

Transient intermediate in the formation of an amorphous metal–organic framework

AF Sapnik, MF Thorne, C Castillo-Blas, L Keenan… - Soft Matter, 2024 - pubs.rsc.org
Amorphous metal–organic frameworks are rarely formed via direct synthesis. Our limited
understanding of their atomic assembly in solution prevents full exploitation of their unique …