Accelerated reaction kinetics in microdroplets: Overview and recent developments
Various organic reactions, including important synthetic reactions involving C–C, C–N, and
C–O bond formation as well as reactions of biomolecules, are accelerated when the …
C–O bond formation as well as reactions of biomolecules, are accelerated when the …
Aqueous microdroplets enable abiotic synthesis and chain extension of unique peptide isomers from free amino acids
DT Holden, NM Morato… - Proceedings of the …, 2022 - National Acad Sciences
Amide bond formation, the essential condensation reaction underlying peptide synthesis, is
hindered in aqueous systems by the thermodynamic constraints associated with …
hindered in aqueous systems by the thermodynamic constraints associated with …
Chemical reaction monitoring by ambient mass spectrometry
J Sun, Y Yin, W Li, O Jin, N Na - Mass Spectrometry Reviews, 2022 - Wiley Online Library
Chemical reactions conducted in different media (liquid phase, gas phase, or surface) drive
developments of versatile techniques for the detection of intermediates and prediction of …
developments of versatile techniques for the detection of intermediates and prediction of …
A critical analysis of electrospray techniques for the determination of accelerated rates and mechanisms of chemical reactions in droplets
Electrospray and Electrosonic Spray Ionization Mass Spectrometry (ESI-MS and ESSI-MS)
have been widely used to report evidence that many chemical reactions in micro-and nano …
have been widely used to report evidence that many chemical reactions in micro-and nano …
Water Charge Transfer Accelerates Criegee Intermediate Reaction with H2O– Radical Anion at the Aqueous Interface
Criegee intermediates (CIs) are important carbonyl oxides that may react with atmospheric
trace chemicals and impact the global climate. The CI reaction with water has been widely …
trace chemicals and impact the global climate. The CI reaction with water has been widely …
Aqueous microdroplets promote C–C bond formation and sequences in the reverse tricarboxylic acid cycle
Y Ju, H Zhang, Y Jiang, W Wang, G Kan, K Yu… - Nature Ecology & …, 2023 - nature.com
The reverse tricarboxylic acid cycle (rTCA) is a central anabolic network that uses carbon
dioxide (CO2) and may have provided complex carbon substrates for life before the advent …
dioxide (CO2) and may have provided complex carbon substrates for life before the advent …
Reaction acceleration promoted by partial solvation at the gas/solution interface
The kinetics of organic reactions of different types in microvolumes (droplets, thin films, and
sealed tubes) show effects of gas/solution interfacial area, reaction molecularity and solvent …
sealed tubes) show effects of gas/solution interfacial area, reaction molecularity and solvent …
Through-Space Electrochemiluminescence Reveals Bubble Forces at Remote Phase Boundaries
Several groups have reported on the curious chemistry and reaction acceleration in
confined volumes. These complex multiphase systems most closely resemble natural …
confined volumes. These complex multiphase systems most closely resemble natural …
Reaction acceleration in electrospray droplets: size, distance, and surfactant effects
Phenylhydrazone formation from isatin is used to examine the effects on the reaction rate of
(i) electrospray emitter distance from the mass spectrometer (MS) inlet,(ii) emitter tip …
(i) electrospray emitter distance from the mass spectrometer (MS) inlet,(ii) emitter tip …
Molecular imprinted polymer-based potentiometric approach for the assay of the co-formulated tetracycline HCl, metronidazole and bismuth subcitrate in capsules and …
Background An anti-H-pylori co-formulated mixture of tetracycline HCl (TET), metronidazole
(MET), and bismuth subcitrate (BSC) is recently available. Only two chromatographic and …
(MET), and bismuth subcitrate (BSC) is recently available. Only two chromatographic and …