Indoles are amongst the most important classes of heteroaromatics in organic chemistry,
commonly found in biologically active natural products and therapeutically useful …

Indole-tethered ynones form an intramolecular electron donor–acceptor complex that can
undergo visible-light-induced charge transfer to promote thiyl radical generation from thiols …

A red-light-mediated nPr-DMQA+-catalyzed cascade intramolecular trifluoromethylation and
dearomatization of indole derivatives with Umemoto's reagent has been developed. This …

The pharmaceutically intriguing spiroindolenines incorporating tetrahydroquinoline were
constructed via a hexafluoroisopropanol-promoted redox-neutral cascade cyclization from …

A gold-catalyzed dearomatization reaction of indole derivatives was realized in the presence
of JohnPhosAuCl/AgOMs to afford a series of spiroindolenines in excellent yields (≤ 99%) …

A novel [4+ 1] and [5+ 1] dearomative spiroannulation has been developed by the use of
commercial naphthols and phenols with dielectrophiles. Various spirocycles, including spiro …

A palladium-catalyzed dearomatization of indoles with alkynes has been developed,
providing an efficient route to access a variety of synthetically useful …

The highly efficient construction of complicated heterocyclic frameworks in an atom‐and step‐
economic manner is still one of the cores of synthetic chemistry. Dearomatization reactions …

Abstract A dearomative [3, 3′]‐sigmatropic rearrangement that converts N‐
alkenylbenzisoxazolines into spirocyclic pyrroline cyclohexadienones has been developed …

Spiro [indole-3, 3′-pyrrolidine]-2′-ones were synthesized via one-pot chloroformylation-
dearomatizing spirocyclization of tryptamine derivatives. Moreover, the “thio” equivalent …