We perform time resolved pump–probe spectroscopy on small halogen molecules ClF, Cl2, Br2, and I2 embedded in rare gas solids (RGS). We find that dissociation, angular …
We present the results of an ab initio study of the interaction of electronically excited NO (A Σ 2+) with rare gas (Rg) atoms. The bound states of each NO (A)–Rg species are determined …
M Gühr, M Bargheer, N Schwentner - Physical review letters, 2003 - APS
A coherent zone boundary phonon (ZBP) of solid Kr (fm= 1.54 TH z) is observed in ultrafast pump-probe spectra of I 2 guest molecules in a Kr crystal. Its phase is stable for at least 10 …
Molecular dynamics simulations and both normal mode and hyperspherical mode analyses of NO-doped Kr solid are carried out in order to get insights into the structural relaxation of …
Z Bihary, R Zadoyan, M Karavitis… - The Journal of chemical …, 2004 - pubs.aip.org
Pump–probe measurements of I2 in solid Ar are reported and analyzed to extract a description of cage response to impulsive excitation, from the gentle kick, up to the breaking …
The dynamics of electronbubble'formation upon excitation of the A (3sσ) Rydberg orbital of NO in solid Ne was investigated by means of femtosecond pump–probe spectroscopy. We …
Molecular-dynamics simulations of structural relaxation in electronically excited NO-doped solid neon are presented. The NO impurity is excited to its lowest A (3 s σ) Rydberg state …
P Pajón-Suárez, G Rojas-Lorenzo… - Chemical physics …, 2006 - Elsevier
The intermolecular potential of the first Rydberg state of the NO–Ne system has been calculated using highly accurate ab initio calculations. The interaction is repulsive with …
Photoexcitation of NO embedded in rare gas matrices triggers a shock-wave like radial perturbation of the surrounding rare gas atoms. In this Letter, we present quantum dynamical …