Progress in organocatalysis with hypervalent iodine catalysts

FV Singh, SE Shetgaonkar, M Krishnan… - Chemical Society …, 2022 - pubs.rsc.org
Hypervalent iodine compounds as environmentally friendly and relatively inexpensive
reagents have properties similar to transition metals. They are employed as alternatives to …

Hypervalent iodine reactions utilized in carbon–carbon bond formations

IFD Hyatt, L Dave, N David, K Kaur… - Organic & …, 2019 - pubs.rsc.org
Advances in hypervalent iodine chemistry have put the field on the precipice of a second
golden age; the first being pioneered in the 1990s. During that period, C–C bond forming …

Asymmetric direct/stepwise dearomatization reactions involving hypervalent iodine reagents

R Kumar, FV Singh, N Takenaga… - Chemistry–An Asian …, 2022 - Wiley Online Library
A remarkable growth in hypervalent iodine‐mediated oxidative transformations as
stoichiometric reagents as well as catalysts has been well‐documented due to their …

Recent Progress in Synthetic Applications of Hypervalent Iodine (III) Reagents

A Yoshimura, VV Zhdankin - Chemical Reviews, 2024 - ACS Publications
Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

Catalyst-substrate helical character matching determines the enantioselectivity in the Ishihara-type iodoarenes catalyzed asymmetric Kita-dearomative …

H Zheng, L Cai, M Pan, M Uyanik… - Journal of the …, 2023 - ACS Publications
Catalyst design has traditionally focused on rigid structural elements to prevent
conformational flexibility. Ishihara's elegant design of conformationally flexible C 2 …

Asymmetric iodine catalysis-mediated enantioselective oxidative transformations

A Claraz, G Masson - Organic & biomolecular chemistry, 2018 - pubs.rsc.org
The implementation of chiral iodine catalysis has tremendously been developed in the field
of asymmetric synthesis over the past decade. It enables the stereoselective creation of C–O …

Merging dearomatization with redox-neutral C (sp 3)–H functionalization via hydride transfer/cyclization: recent advances and perspectives

F Hu, YB Shen, L Wang, SS Li - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
Dearomatization and direct C (sp3)–H functionalization represent two hot research fields in
organic synthesis, the merging of which is among the most challenging but appealing topics …

Applications of oxone® in organic synthesis: an emerging green reagent of modern era

S Alvi, V Jayant, R Ali - ChemistrySelect, 2022 - Wiley Online Library
Presently, the major cornerstone of the research community is to develop green as well as
sustainable protocols involving inexpensive catalysts and/or reagents without the usage of …

High-performance ammonium hypoiodite/oxone catalysis for enantioselective oxidative dearomatization of arenols

M Uyanik, T Kato, N Sahara, O Katade, K Ishihara - ACS Catalysis, 2019 - ACS Publications
A high-performance enantioselective quaternary ammonium hypoiodite catalysis was
developed for the dearomatization of arenols using oxone as an environmentally benign …

Divergent biomimetic total syntheses of ganocins A–C, ganocochlearins C and D, and cochlearol T

H Shao, X Gao, ZT Wang, Z Gao… - Angewandte Chemie …, 2020 - Wiley Online Library
A divergent synthetic approach to six Ganoderma meroterpenoids, namely ganocins A–C,
ganocochlearins C and D, and cochlearol T, has been developed for the first time. This …