Chiral metal–organic frameworks

W Gong, Z Chen, J Dong, Y Liu, Y Cui - Chemical Reviews, 2022 - ACS Publications
In the past two decades, metal–organic frameworks (MOFs) or porous coordination polymers
(PCPs) assembled from metal ions or clusters and organic linkers via metal–ligand …

Metal–organic cages for molecular separations

D Zhang, TK Ronson, YQ Zou, JR Nitschke - Nature Reviews Chemistry, 2021 - nature.com
Separation technology is central to industries as diverse as petroleum, pharmaceuticals,
mining and life sciences. Metal–organic cages, a class of molecular containers formed via …

Guest-driven self-assembly and chiral induction of photofunctional lanthanide tetrahedral cages

SJ Hu, XQ Guo, LP Zhou, DN Yan… - Journal of the …, 2022 - ACS Publications
Chiral luminescent lanthanide–organic cages have many potential applications in
enantioselective recognition, sensing, and asymmetric catalysis. However, due to the …

Supramolecular helical systems: helical assemblies of small molecules, foldamers, and polymers with chiral amplification and their functions

E Yashima, N Ousaka, D Taura, K Shimomura… - Chemical …, 2016 - ACS Publications
In this review, we describe the recent advances in supramolecular helical assemblies
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …

Permanently microporous metal–organic polyhedra

AJ Gosselin, CA Rowland, ED Bloch - Chemical reviews, 2020 - ACS Publications
As compared to porous network solids, including metal–organic frameworks, covalent–
organic frameworks, porous aromatic frameworks, and zeolites, porous molecular materials …

Free-standing homochiral 2D monolayers by exfoliation of molecular crystals

J Dong, L Liu, C Tan, Q Xu, J Zhang, Z Qiao, D Chu… - Nature, 2022 - nature.com
Two-dimensional materials with monolayer thickness and extreme aspect ratios are sought
for their high surface areas and unusual physicochemical properties. Liquid exfoliation is a …

Recent developments in the preparation and chemistry of metallacycles and metallacages via coordination

TR Cook, PJ Stang - Chemical reviews, 2015 - ACS Publications
The continued development of molecular architectures of consequence to both longstanding
and newly recognized problems demands ever evolving synthetic routes, characterizations …

Hetero-and homointerlocked metal–organic cages

Y Li, H Jiang, W Zhang, X Zhao, M Sun… - Journal of the …, 2024 - ACS Publications
Interlocked molecular assemblies constitute a captivating ensemble of chemical topologies,
comprising two or more separate components that exhibit remarkably intricate structures …

Bifunctionalized Metal–Organic Frameworks for Pore‐Size‐Dependent Enantioselective Sensing

Z Han, K Wang, H Min, J Xu, W Shi… - Angewandte …, 2022 - Wiley Online Library
Porosity is a fundamental property of metal–organic frameworks (MOFs). However, the role
of the pore size has always been underestimated in MOF‐based luminescent sensors for …

Chiral BINOL-based covalent organic frameworks for enantioselective sensing

X Wu, X Han, Q Xu, Y Liu, C Yuan, S Yang… - Journal of the …, 2019 - ACS Publications
Covalent organic frameworks (COFs) have emerged as a novel platform for material design
and functional explorations, but it remains a challenge to synthetically functionalize targeted …