A circular economy approach to plastic waste

J Payne, P McKeown, MD Jones - Polymer Degradation and Stability, 2019 - Elsevier
Growing environmental concerns associated with the accumulation of plastic waste in the
natural environment has incentivised considerable research into renewable alternatives …

Controlling polymer stereochemistry in ring-opening polymerization: a decade of advances shaping the future of biodegradable polyesters

MJL Tschan, RM Gauvin, CM Thomas - Chemical Society Reviews, 2021 - pubs.rsc.org
This review highlights recent developments in the field of biodegradable polymeric materials
intended to replace non-degradable conventional plastics, focusing on studies from the last …

Recent trends in catalytic polymerizations

DJ Walsh, MG Hyatt, SA Miller, D Guironnet - ACS Catalysis, 2019 - ACS Publications
Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …

Recent advances in enantioselective ring-opening polymerization and copolymerization

X Xie, Z Huo, E Jang, R Tong - Communications Chemistry, 2023 - nature.com
Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy
for manipulating polymer properties. Controlled synthetic routes to prepare degradable …

Bayesian-optimization-assisted discovery of stereoselective aluminum complexes for ring-opening polymerization of racemic lactide

X Wang, Y Huang, X Xie, Y Liu, Z Huo, M Lin… - Nature …, 2023 - nature.com
Stereoselective ring-opening polymerization catalysts are used to produce degradable
stereoregular poly (lactic acids) with thermal and mechanical properties that are superior to …

Synthesis of biodegradable polymers: a review on the use of schiff-base metal complexes as catalysts for the ring opening polymerization (ROP) of cyclic esters

O Santoro, X Zhang, C Redshaw - Catalysts, 2020 - mdpi.com
This review describes the recent advances (from 2008 onwards) in the use of Schiff-base
metal complexes as catalysts for the ring opening polymerization (ROP) of cyclic esters. The …

Recent advances in metal‐mediated stereoselective ring‐opening polymerization of functional cyclic esters towards well‐defined poly (hydroxy acid) s: from …

H Li, RM Shakaroun, SM Guillaume… - … –A European Journal, 2020 - Wiley Online Library
Poly (hydroxy acid) s are a family of biocompatible and (bio) degradable polyesters with
various outcomes in different domains of application. To date, poly (hydroxy acid) s are best …

Recent progress in the application of group 1, 2 & 13 metal complexes as catalysts for the ring opening polymerization of cyclic esters

J Gao, D Zhu, W Zhang, GA Solan, Y Ma… - Inorganic Chemistry …, 2019 - pubs.rsc.org
High performance biodegradable polymers (eg, aliphatic polyesters) that can display
properties that rival polyolefins are seen as future high demand materials for a variety of …

Metal‐size influence in iso‐selective lactide polymerization

C Bakewell, AJP White, NJ Long… - Angewandte …, 2014 - Wiley Online Library
Iso‐selective initiators for the ring‐opening polymerization (ROP) of rac‐lactide are rare
outside of Group 13. We describe the first examples of highly iso‐selective lutetium initiators …

Simple and Efficient Zinc Catalysts for Synthesis and Chemical Degradation of Polyesters

F Santulli, D Pappalardo, M Lamberti… - ACS Sustainable …, 2023 - ACS Publications
A series of zinc complexes supported by tridentate imino-phenolate ligands with different
substituents on the phenolate ring and bearing a pyridyl ring as an additional coordinative …