Over the last few decades, conical intersections (CoIns) have grown from theoretical
curiosities into common mechanistic features of photochemical reactions, whose function is …

Since the seminal report by Adachi and co-workers in 2012, there has been a veritable
explosion of interest in the design of thermally activated delayed fluorescence (TADF) …

Rationalizing the photochemistry of nucleobases where an oxygen is replaced by a heavier
atom is essential for applications that exploit near-unity triplet quantum yields. Herein, we …

Previously, the MS‐CASPT2 method was performed to study the static and qualitative
photophysics of tellurium‐substituted cytosine (TeC). To get quantitative information, we …

The substitution of oxygen with chalcogen in carbonyl group (s) of canonical nucleobases
gives an impressive triplet generation, enabling their promising applications in medicine and …

Achieving intersystem crossing (ISC) through structural tuning in biological systems is an
evolving area for therapeutic and materials research. Eumelanin, a natural pigment, offers …

Selenium nucleic acids possess unique properties and have been demonstrated to have a
wide range of applications such as in DNA X-ray crystallography and novel medical …

The photophysical relaxation mechanisms of 1-cyclohexyluracil, in vacuum and water, were
investigated by employing the Multi-State CASPT2 (MS-CASPT2, Multi-State Complete …

A novel tellurium (Te) containing fluorophore, 1 and its nickel (2) and copper (3) containing
metal organic complex (MOC) have been synthesized to exploit their structural and optical …

Numerous chlorophyll-based derivatives have found applications in the dye and
pharmaceutical industries. Here, we report the synthesis of a poly-hydroxyl substituted …