Oxygen loss in layered oxide cathodes for Li-ion batteries: Mechanisms, effects, and mitigation

H Zhang, H Liu, LFJ Piper, MS Whittingham… - Chemical …, 2022 - ACS Publications
Layered lithium transition metal oxides derived from LiMO2 (M= Co, Ni, Mn, etc.) have been
widely adopted as the cathodes of Li-ion batteries for portable electronics, electric vehicles …

Pushing the limit of 3d transition metal-based layered oxides that use both cation and anion redox for energy storage

M Zhang, DA Kitchaev, Z Lebens-Higgins… - Nature Reviews …, 2022 - nature.com
Intercalation chemistry has dominated electrochemical energy storage for decades, and
storage capacity worldwide has now reached the terawatt-hour level. State-of-the-art …

[PDF][PDF] Progress on modification strategies of layered lithium-rich cathode materials for high energy lithium-ion batteries

H Lu, R Hou, S Chu, H Zhou, S Guo - Acta Phys.-Chim. Sin, 2023 - whxb.pku.edu.cn
High-performance rechargeable lithium-ion batteries have been widely used in portable
electronic devices, electric vehicles and other fields of electrochemical energy storage …

Origin of structural degradation in Li-rich layered oxide cathode

T Liu, J Liu, L Li, L Yu, J Diao, T Zhou, S Li, A Dai… - Nature, 2022 - nature.com
Li-and Mn-rich (LMR) cathode materials that utilize both cation and anion redox can yield
substantial increases in battery energy density,–. However, although voltage decay issues …

Reactive boride infusion stabilizes Ni-rich cathodes for lithium-ion batteries

M Yoon, Y Dong, J Hwang, J Sung, H Cha, K Ahn… - Nature Energy, 2021 - nature.com
Engineered polycrystalline electrodes are critical to the cycling stability and safety of lithium-
ion batteries, yet it is challenging to construct high-quality coatings at both the primary-and …

Pushing Lithium Cobalt Oxides to 4.7 V by Lattice‐Matched Interfacial Engineering

X Yang, C Wang, P Yan, T Jiao, J Hao… - Advanced Energy …, 2022 - Wiley Online Library
The utilization of high‐voltage LiCoO2 is imperative to break the bottleneck of the practical
energy density of lithium‐ion batteries. However, LiCoO2 suffers from severe structural and …

Understanding Co roles towards developing Co-free Ni-rich cathodes for rechargeable batteries

T Liu, L Yu, J Liu, J Lu, X Bi, A Dai, M Li, M Li, Z Hu… - Nature energy, 2021 - nature.com
Current bottlenecks in cobalt (Co) supply have negatively impacted commercial battery
production and inspired the development of cathode materials that are less reliant on Co …

Improving the oxygen redox reversibility of Li-rich battery cathode materials via Coulombic repulsive interactions strategy

Q Li, D Ning, D Wong, K An, Y Tang, D Zhou… - Nature …, 2022 - nature.com
The oxygen redox reaction in lithium-rich layered oxide battery cathode materials generates
extra capacity at high cell voltages (ie,> 4.5 V). However, the irreversible oxygen release …

Oxygen vacancies unfold the catalytic potential of NiFe-layered double hydroxides by promoting their electronic transport for oxygen evolution reaction

H Zhang, L Wu, R Feng, S Wang, CS Hsu, Y Ni… - ACS …, 2023 - ACS Publications
Oxygen vacancies (Ov) engineering has demonstrated tremendous power to expedite
electrocatalytic kinetics for oxygen evolution reaction (OER). The mechanism is elusive, and …

Lithium–oxygen batteries and related systems: potential, status, and future

WJ Kwak, Rosy, D Sharon, C Xia, H Kim… - Chemical …, 2020 - ACS Publications
The goal of limiting global warming to 1.5° C requires a drastic reduction in CO2 emissions
across many sectors of the world economy. Batteries are vital to this endeavor, whether used …