Molecular main group metal hydrides

MMD Roy, AA Omana, ASS Wilson, MS Hill… - Chemical …, 2021 - ACS Publications
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …

Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials

EM Leitao, T Jurca, I Manners - Nature chemistry, 2013 - nature.com
Catalytic reactions that enable the formation of new bonds to carbon centres play a
pervasive role in the state-of-the-art synthesis of organic molecules and macromolecules. In …

Mechanisms of metal-catalyzed dehydrocoupling reactions

R Waterman - Chemical Society Reviews, 2013 - pubs.rsc.org
This review summarizes selected mechanistic insight garnered from reactions that form
bonds between main group elements with liberation of hydrogen, dehydrocoupling or …

Transition‐Metal‐Catalyzed Dehydrocoupling: A Convenient Route to Bonds between Main‐Group Elements

TJ Clark, K Lee, I Manners - Chemistry–A European Journal, 2006 - Wiley Online Library
The development of transition‐metal‐catalyzed dehydrocoupling reactions as a synthetic
method for the formation of main‐group element–element bonds provides an increasingly …

Monomeric organoantimony (I) and organobismuth (I) compounds stabilized by an NCN chelating ligand: Syntheses and structures

P Šimon, F De Proft, R Jambor, A Růžička… - Angewandte Chemie …, 2010 - infona.pl
One on one: A combination of steric effects and M N interactions of a rigid NCN pincer
ligand allows the isolation and characterization of monomeric stibinidene and …

Quest for stable or masked pnictinidenes: Emerging and exciting class of group 15 compounds

L Dostál - Coordination Chemistry Reviews, 2017 - Elsevier
The chemistry of low-valent main group compounds represents one of the most exciting and
quickly developing areas in the field of organometallic and organoelement chemistry. In this …

Dehydrocoupling reactions of borane− secondary and− primary amine adducts catalyzed by group-6 carbonyl complexes: formation of aminoboranes and borazines

Y Kawano, M Uruichi, M Shimoi, S Taki… - Journal of the …, 2009 - ACS Publications
Photoirradiation of a solution of BH3· NHR2 (1a: R= Me, 1b: R= 1/2C4H8, 1c: R= 1/2C5H10,
1f: R= Et) containing a catalytic amount of a group-6 metal carbonyl complex,[M (CO) 6](M …

Antimony-ligated dysprosium single-molecule magnets as catalysts for stibine dehydrocoupling

T Pugh, NF Chilton, RA Layfield - Chemical Science, 2017 - pubs.rsc.org
Single-molecule magnets (SMMs) are coordination compounds that exhibit magnetic
bistability below a characteristic blocking temperature. Research in this field continues to …

Recent advances in catalytic pnictogen bond forming reactions via dehydrocoupling and hydrofunctionalization

MB Reuter, DM Seth, DR Javier-Jiménez… - Chemical …, 2023 - pubs.rsc.org
An examination of several catalytic reactions among the group 15 elements is presented.
The connections between the chemistry of the pnictogens can sometimes be challenging …

Catalytic P H Activation by Ti and Zr Catalysts

JD Masuda, AJ Hoskin, TW Graham… - … A European Journal, 2006 - Wiley Online Library
Catalytic dehydrocoupling of phosphines was investigated using the anionic zirconocene
trihydride salts [Cp* 2Zr (μ‐H) 3Li] 3 (1 a) or [Cp* 2Zr (μ‐H) 3K (thf) 4](1 b), and the …