Prebiotic astrochemistry and the formation of molecules of astrobiological interest in interstellar clouds and protostellar disks

SA Sandford, M Nuevo, PP Bera, TJ Lee - Chemical reviews, 2020 - ACS Publications
Despite the generally hostile nature of the environments involved, chemistry does occur in
space. Molecules are seen in environments that span a wide range of physical and chemical …

The GRETOBAPE gas-phase reaction network: the importance of being exothermic

L Tinacci, S Ferrada-Chamorro… - The Astrophysical …, 2023 - iopscience.iop.org
The gas-phase reaction networks are the backbone of astrochemical models. However, due
to their complexity and nonlinear impact on the astrochemical modeling, they can be the first …

Formation of complex organic molecules in molecular clouds: acetaldehyde, vinyl alcohol, ketene, and ethanol via the “energetic” processing of C2H2 ice

KJ Chuang, G Fedoseev, C Scirè, GA Baratta… - Astronomy & …, 2021 - aanda.org
Context. The simultaneous detection of organic molecules of the form C 2 H n O, such as
ketene (CH 2 CO), acetaldehyde (CH 3 CHO), and ethanol (CH 3 CH 2 OH), toward early …

Exploitation of synchrotron radiation photoionization mass spectrometry in the analysis of complex organics in interstellar model ices

C Zhu, H Wang, I Medvedkov, J Marks… - The Journal of …, 2022 - ACS Publications
Unravelling the generation of complex organic molecules (COMs) on interstellar
nanoparticles (grains) is essential in establishing predictive astrochemical reaction networks …

Broadband spectroscopy of astrophysical ice analogues-I. Direct measurement of the complex refractive index of CO ice using terahertz time-domain spectroscopy

BM Giuliano, AA Gavdush, B Müller, KI Zaytsev… - Astronomy & …, 2019 - aanda.org
Context. Reliable, directly measured optical properties of astrophysical ice analogues in the
infrared and terahertz (THz) range are missing from the literature. These parameters are of …

Role of suprathermal chemistry on the evolution of carbon oxides and organics within interstellar and cometary ices

BC Ferrari, K Slavicinska… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus Laboratory-based experimental astrochemistry regularly entails simulation of
astrophysical environments whereby low-temperature condensed ices are exposed to …

Formation of chiral CO polyhedral crystals on icy interstellar grains

A Kouchi, M Tsuge, T Hama, H Niinomi… - Monthly notices of …, 2021 - academic.oup.com
The crystallinity and morphology of solid carbon monoxide (CO) on icy interstellar grains
were examined by observing the deposition, crystallization, and UV and electrons irradiation …

Density and infrared band strength of interstellar carbon monoxide (CO) ice analogues

C González Díaz, H Carrascosa… - Monthly Notices of …, 2022 - academic.oup.com
The motivation to study experimentally CO ice under mimicked interstellar conditions is
supported by the large CO gas abundances and ubiquitous presence of CO in icy grain …

Bombardment of CO Ice by Cosmic Rays. I. Experimental Insights into the Microphysics of Molecule Destruction and Sputtering

AV Ivlev, BM Giuliano, Z Juhász… - The Astrophysical …, 2023 - iopscience.iop.org
We present a dedicated experimental study of microscopic mechanisms controlling
radiolysis and sputtering of astrophysical ices upon bombardment by cosmic-ray ions. Such …

Ion irradiation triggers the formation of the precursors of complex organics in space-The case of formaldehyde and acetaldehyde

RG Urso, E Hénault, R Brunetto, D Baklouti… - Astronomy & …, 2022 - aanda.org
Context. Cosmic rays and solar energetic particles induce changes in the composition of
compounds frozen onto dust grains in the interstellar medium (ISM), in comets, and on the …