Recent developments of photoactive Cu (I) and Ag (I) complexes with diphosphine and related ligands

H Takeda, A Kobayashi, K Tsuge - Coordination Chemistry Reviews, 2022 - Elsevier
In the past two decades, emissive Cu (I) complexes have been synthesized with various
ligands, revealing their interesting and useful photophysical properties such as high …

Non-covalent intramolecular interactions through ligand-design promoting efficient photoluminescence from transition metal complexes

IO Koshevoy, M Krause, A Klein - Coordination Chemistry Reviews, 2020 - Elsevier
Ligand design allows arranging ligand entities and functional groups in order to generate a
plethora of non-covalent interactions such as π stacking, H bridging, and Lewis acid-base …

“Quick-Silver” from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes

R Hamze, S Shi, SC Kapper… - Journal of the …, 2019 - ACS Publications
A systematic study is presented on the physical and photophysical properties of
isoelectronic and isostructural Cu, Ag, and Au complexes with a common amide (N …

Cu (I) and Ag (I) complexes with a new type of rigid tridentate N, P, P-ligand for thermally activated delayed fluorescence and OLEDs with high external quantum …

M Klein, N Rau, M Wende, J Sundermeyer… - Chemistry of …, 2020 - ACS Publications
Neutral Cu (I) and Ag (I) complexes with a new rigid tridentate N, P, P ligand (dmpzpp, 3, 5-
dimethyl-1-(2-((2-(di-o-tolyl) phosphanyl)(o-tolyl)-phosphanyl) phenyl)-1 H-pyrazole), giving …

Understanding and designing thermally activated delayed fluorescence emitters: beyond the energy gap approximation

J Eng, TJ Penfold - The Chemical Record, 2020 - Wiley Online Library
In this article recent progress in the development of molecules exhibiting Thermally
Activated Delayed Fluorescence (TADF) is discussed with a particular focus upon their …

Silver (I)–Organic Frameworks Showing Remarkable Thermo-, Solvato-And Vapochromic Phosphorescence As Well As Reversible Solvent-Driven 3D-to-0D …

MI Rogovoy, AS Berezin, DG Samsonenko… - Inorganic …, 2021 - ACS Publications
A series of isoreticular Ag (I) luminescent metal–organic frameworks (LMOFs),{[Ag2L2
(CH3CN) 2](X) 2} n (X= ClO4, OTf, and BF4), has been designed, exploiting diphenyl (2 …

Tetradentate CCNN Ligand-Containing Gold(III) Complexes with Orange to Deep-Red Thermally Activated Delayed Fluorescence (TADF) and Their …

WK Kwok, LK Li, SL Lai, MY Leung… - Journal of the …, 2023 - ACS Publications
A new class of thermally activated delayed fluorescence (TADF) tetradentate C∧ C∧ N∧ N
ligand-containing gold (III) complexes containing acridinyl moieties has been designed and …

Sky-blue thermally activated delayed fluorescence (TADF) based on Ag (I) complexes: Strong solvation-induced emission enhancement

AV Artem'ev, MZ Shafikov, A Schinabeck… - Inorganic Chemistry …, 2019 - pubs.rsc.org
A new Ag (I) complex based on tris (2-pyridyl) phosphine (Py3P),[Ag2 (Py3P) 3 (SCN) 2],
has been synthesized and chemically characterized. Theoretical calculations and …

Dual‐Phosphorescent Heteroleptic Silver (I) Complex in Long‐Lasting Red Light‐Emitting Electrochemical Cells

S Lipinski, LM Cavinato, T Pickl, G Biffi… - Advanced Optical …, 2023 - Wiley Online Library
The design of red‐emitting silver (I) complexes and their implementation in thin‐film lighting
are still challenging as (i) their high ligand‐field splitting energy leads to high‐energy …

Ag (i) emitters with ultrafast spin-flip dynamics for high-efficiency electroluminescence

A Ying, N Li, X Chen, J Xia, C Yang, S Gong - Chemical Science, 2025 - pubs.rsc.org
Carbene-metal-amide (CMA) complexes are appealing emitters for organic light-emitting
diodes (OLEDs). However, little is known about silver (I)-CMA complexes, particularly …