Carbohydrates, which are ubiquitously distributed throughout the three domains of life, play
significant roles in a variety of vital biological processes. Access to unique and …

Glycosaminoglycans (GAGs) as one major part of the glycocalyx are involved in many
essential biological cell processes, as well as in many courses of diseases. Because of the …

This tutorial review surveys the use of thioglycosides in the development of sequential
glycosylation methodologies, with a focus on chemoselective, orthogonal and iterative …

The presence of heterocyclic moieties in all kinds of organic compounds of interest in
biology, pharmacology, optics, electronics, material sciences, and so on is sufficiently known …

A novel one-pot relay glycosylation has been established. The protocol is characterized by
the construction of two glycosidic bonds with only one equivalent of triflic anhydride. This …

Partially protected thioglycuronic acids are prepared efficiently by chemo-and regioselective
oxidation of the corresponding thioglycosides using the TEMPO/BAIB reagent combination …

A novel flexible assembly strategy is described for the modular synthesis of heparin and
heparan sulfates. The reported strategy uses monomeric building bocks to construct the …

Saccharide synthesis is a formidable task for synthetic chemists. Although in recent years
many advances have been made in this area, development of more convenient and efficient …

Although glycoscientists have learned over the years how to isolate certain classes of
naturally occurring complex carbohydrates, the availability of pure natural isolates, remains …

Glycosyl triflates, which serve as important intermediates in glycosylation reactions, were
generated and accumulated by the low-temperature electrochemical oxidation of …