Chemical bonding and bonding models of main-group compounds

L Zhao, S Pan, N Holzmann, P Schwerdtfeger… - Chemical …, 2019 - ACS Publications
The focus of this review is the presentation of the most important aspects of chemical
bonding in molecules of the main group atoms according to the current state of knowledge …

Spin–orbit coupling and intersystem crossing in molecules

CM Marian - Wiley Interdisciplinary Reviews: Computational …, 2012 - Wiley Online Library
Many light‐induced molecular processes involve a change in spin state and are formally
forbidden in non‐relativistic quantum theory. To make them happen, spin–orbit coupling …

Main group redox catalysis of organopnictogens: vertical periodic trends and emerging opportunities in group 15

JM Lipshultz, G Li, AT Radosevich - Journal of the American …, 2021 - ACS Publications
A growing number of organopnictogen redox catalytic methods have emerged—especially
within the past 10 years—that leverage the plentiful reversible two-electron redox chemistry …

Thermal decomposition of the non-interstitial hydrides for the storage and production of hydrogen

W Grochala, PP Edwards - Chemical reviews, 2004 - ACS Publications
Hydrogen is nature's simplest, lightest atom, consisting of a single proton and a single
electron. 2 Paradoxically, this “simplicity” in electronic structure leads to unique …

The accuracy of the pseudopotential approximation. II. A comparison of various core sizes for indium pseudopotentials in calculations for spectroscopic constants of …

T Leininger, A Nicklass, H Stoll, M Dolg… - The Journal of …, 1996 - pubs.aip.org
Small-and medium-core pseudopotentials representing Ar3d10-and Kr-like cores,
respectively, have been adjusted for the In atom, supplementing the energy-consistent three …

Perspective: relativistic effects

J Autschbach - The Journal of chemical physics, 2012 - pubs.aip.org
This perspective article discusses some broadly-known and some less broadly-known
consequences of Einstein's special relativity in quantum chemistry, and provides a brief …

The periodic table and the physics that drives it

P Schwerdtfeger, OR Smits, P Pyykkö - Nature reviews chemistry, 2020 - nature.com
Mendeleev's introduction of the periodic table of elements is one of the most important
milestones in the history of chemistry, as it brought order into the known chemical and …

Hydrides of the main-group metals: New variations on an old theme

S Aldridge, AJ Downs - Chemical reviews, 2001 - ACS Publications
For an atom with such a uniquely simple electronic makeup, hydrogen shows remarkable
mutability as a ligand. As a one-electron substituent with no significant potential for π-type …

Molecular structure of metal halides

M Hargittai - Chemical Reviews, 2000 - ACS Publications
Molecular Structure of Metal Halides | Chemical Reviews ACS ACS Publications C&EN CAS
Find my institution Log In Chemical Reviews ACS Publications. Most Trusted. Most Cited. Most …

A novel photoluminescent Cd (II)–organic framework exhibiting rapid and efficient multi-responsive fluorescence sensing for trace amounts of Fe 3+ ions and some …

YJ Yang, MJ Wang, KL Zhang - Journal of Materials Chemistry C, 2016 - pubs.rsc.org
The first photoluminescent Cd (II)–organic framework {[Cd (5-asba)(bimb)]} n (1) based on a
multi-functional ligand, 2-amino-5-sulfobenzoic acid (H25-asba), has been successfully …