Alkene functionalisation is a powerful strategy that has enabled access to a wide array of
compounds including valuable pharmaceuticals and agrochemicals. The reactivity of the …

Organoboron compounds have a wide-range of applications in synthetic methodologies,
natural products, and bioactive molecule synthesis. The sensitivity of boronic acid toward …

Compounds bearing both boryl and amino groups at distal positions are invaluable
synthons for synthesizing pharmaceuticals, drug candidates, and natural products, but their …

Secondary α, α‐dialkyl boronates are widely used due to their great versatility. Herein we
report an unprecedented deoxygenative alkylboration of aldehydes, a facile method to …

Direct transformations of readily available amines or amides via C–H bond functionalization
could provide a fast route for accessing complex molecules. While various groups have …

While chiral allylic organophosphorus compounds are widely utilized in asymmetric
catalysis and for accessing bioactive molecules, their synthetic methods are still very limited …

Asymmetric multicomponent reactions are considered as efficient protocols for constructing
complex chiral molecules because of their step‐and atom‐economy. Nickel‐catalyzed …

The first nickel bis-boryl complexes cis-[Ni (iPr2ImMe) 2 (Bcat) 2], cis-[Ni (iPr2ImMe) 2 (Bpin)
2] and cis-[Ni (iPr2ImMe) 2 (Beg) 2] are reported, which were prepared via the reaction of a …

The construction of C–C and C–X (X= N, O, Si, etc.) bonds is an important field in organic
synthesis and methodology. In recent decades, studies on transition metal-catalyzed …

Borylation has become a powerful method to synthesize organoboranes as versatile
building blocks in organic synthesis, medicinal chemistry, and materials science. Copper …