[图书][B] Electroanalytical Chemistry: A Series of Advances: Volume 23

AJ Bard, CG Zoski - 2010 - taylorfrancis.com
Electroanalytical chemists and others are concerned not only with the application of new
and classical techniques to analytical problems, but also with the fundamental theoretical …

Determining the Gibbs Energy of Ion Transfer Across Water–Organic Liquid Interfaces with Three‐Phase Electrodes

F Scholz, R Gulaboski - ChemPhysChem, 2005 - Wiley Online Library
Ions can be transferred between immiscible liquid phases across a common interface, with
the help of a three‐electrode potentiostat, when one phase is an organic droplet attached to …

[图书][B] Electrochemistry of immobilized particles and droplets

F Scholz, U Schröder, R Gulaboski… - 2005 - Springer
Fundamental Electrode Kinetics is represented by treatments of reactions such as O2+ 4H++
4e À Æ 2H2O, still important in the theory of electrocatalysis. As for the cutting edge in …

Intrinsic structure and dynamics of the water/nitrobenzene interface

M Jorge, MNDS Cordeiro - The Journal of Physical Chemistry C, 2007 - ACS Publications
In this paper we present results of a detailed and systematic molecular dynamics study of the
water/nitrobenzene interface. Using a simple procedure to eliminate fluctuations of the …

Descriptors for ions and ion-pairs for use in linear free energy relationships

MH Abraham, WE Acree Jr - Journal of Chromatography A, 2016 - Elsevier
The determination of Abraham descriptors for single ions is reviewed, and equations are
given for the partition of single ions from water to a number of solvents. These ions include …

Gibbs energies of transfer of chiral anions across the interface water| chiral organic solvent determined with the help of three-phase electrodes

F Scholz, R Gulaboski - Faraday Discussions, 2005 - pubs.rsc.org
For the first time the differences in free energies have been experimentally determined for
the solvation of two enantiomeric ions in two enantiomeric solvents. Three-phase electrodes …

The transfer of neutral molecules, ions and ionic species from water to wet octanol

MH Abraham, WE Acree Jr - Physical Chemistry Chemical Physics, 2010 - pubs.rsc.org
Partition coefficients for transfer from water to wet octanol have been set out for permanent
ions, and for ionic species derived from neutral molecules by loss or acceptance of a proton …

Evaluation of the lipophilic properties of opioids, amphetamine-like drugs, and metabolites through electrochemical studies at the interface between two immiscible …

R Gulaboski, MNDS Cordeiro, N Milhazes… - Analytical …, 2007 - Elsevier
For the first time, the partition coefficients of the ionized forms of several opioids,
amphetamine-like drugs, and their metabolites were determined by studying their ionic …

Redox properties of the calcium chelator Fura-2 in mimetic biomembranes

R Gulaboski, CM Pereira, MNDS Cordeiro, AF Silva… - Cell calcium, 2008 - Elsevier
Fura-2 is one of the most commonly used fluorescent dyes to analyze the cytosolic Ca2+
concentration ([Ca2+] i) of living cells. Fura-2-dependent measurements of [Ca2+] i are …

Detection of acetylcholine at nanoscale NPOE/water liquid/liquid interface electrodes

HD Jetmore, CB Milton, ES Anupriya, R Chen… - Analytical …, 2021 - ACS Publications
The interface between two immiscible electrolyte solutions (ITIES) has become a very
powerful analytical platform for sensing a diverse range of chemicals (eg, metal ions and …