The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

During the past decade we have witnessed the rapid development and understanding of
living radical polymerization (LRP)(or reversible deactivation radical polymerizations …

The mechanisms of most organic reactions are considered to proceed by two-electron
transfer pathways, even though both biology and radical chemistry rely extensively on one …

The most fundamental aspects of single-electron transfer (SET) principles are presented.
They are discussed according to different definitions used by expert practitioners and are …

Cu (0)-mediated living radical polymerization or single electron transfer living radical
polymerization (Cu (0)-mediated LRP or SET-LRP) is a versatile polymerization technique …

Redox polymerizations are of huge importance throughout academic and industrial polymer
science. Many authors propose the reaction of reducing (Red) and oxidizing (Ox) agents to …

The combination of copper (0) mediated living radical polymerization (Cu (0)-LRP) with thiol–
halogen, thiol–epoxy and copper catalysed alkyne azide coupling (CuAAC) click chemistry …

Single electron transfer–living radical polymerization (SET-LRP) represents a robust and
versatile tool for the synthesis of vinyl polymers with well-defined topology and chain end …

Photoinduced living radical polymerization of acrylates is achieved upon UV irradiation
(λmax≈ 360 nm) in the presence of an aliphatic tertiary amine ligand (Me6-Tren) in the …

The self-organizable dendron (4-3, 4-3, 5) 12G2X with X=–CO2CH3 and–CH2OH, an
already classic dendron, facilitating the formation of a large diversity of columnar hexagonal …