Organofluorine chemistry: Promising growth areas and challenges

LV Politanskaya, GA Selivanova… - Russian Chemical …, 2019 - iopscience.iop.org
Currently, the chemistry of organofluorine compounds is a leading and rapidly developing
area of organic chemistry. Fluorine present in a molecule largely determines its specific …

Rhodium (III)-catalyzed arene and alkene C− H bond functionalization leading to indoles and pyrroles

DR Stuart, P Alsabeh, M Kuhn… - Journal of the American …, 2010 - ACS Publications
Recently, the rhodium (III)-complex [Cp* RhCl2] 2 1 has provided exciting opportunities for
the efficient synthesis of aromatic heterocycles based on a rhodium-catalyzed C− H bond …

Trifluoromethanesulfonic acid in organic synthesis

AN Kazakova, AV Vasilyev - Russian Journal of Organic Chemistry, 2017 - Springer
The review analyzes data published in the past decade on the use of
trifluoromethanesulfonic acid (triflic acid, CF 3 SO 3 H, TfOH) in organic synthesis, in …

Recent Advances for the Synthesis of Dihydroquinolin-2(1H)-ones via Catalytic Annulation of α,β-Unsaturated N-Arylamides

YN Niu, LS Tian, HZ Lv, PG Li - Catalysts, 2023 - mdpi.com
Dihydroquinolin-2 (1 H)-ones (DHQOs) represent a class of valuable bioactive compounds
with six-membered nitrogen-containing heterocyclic structures. The development of simple …

Bromination of quinolin-2 (1H)-ones fluorinated on the benzene moiety

FK Verkhov, AD Skolyapova, VI Krasnov… - Journal of Fluorine …, 2023 - Elsevier
Bromination of ten known fluorinated quinolin-2 (1H)-ones by the KBrO 3/HBr system is
investigated. If there is no F atom in the position 6 of substrate, the Br atom is introduced into …

A facile and efficient method for the selective deacylation of N-arylacetamides and 2-chloro-N-arylacetamides catalyzed by SOCl2

GB Wang, LF Wang, CZ Li, J Sun, GM Zhou… - Research on Chemical …, 2012 - Springer
Thionyl chloride efficiently and selectively promoted the deacylation of N-arylacetamides
and 2-chloro-N-arylacetamides, under anhydrous conditions, without effecting the ester …

Superelectrophilic activation of N-aryl amides of 3-arylpropynoic acids: synthesis of quinolin-2 (1H)-one derivatives

DS Ryabukhin, LY Gurskaya, GK Fukin, AV Vasilyev - Tetrahedron, 2014 - Elsevier
The superelectrophilic activation of N-aryl amides of 3-arylpropynoic acids by Bronsted
superacids (CF 3 SO 3 H, HSO 3 F) or strong Lewis acids AlX 3 (X= Cl, Br) results in the …

DFT insights into superelectrophilic activation of α, β-unsaturated nitriles and ketones in superacids

AM Genaev, GE Salnikov, KY Koltunov - Organic & Biomolecular …, 2022 - pubs.rsc.org
Superelectrophilic activation of α, β-unsaturated carbonyl compounds and their isoelectronic
analogs, proceeding normally under superacidic conditions, have led to a great variety of …

Synthesis, In Silico and In Vivo Toxicity Assessment of Functionalized Pyridophenanthridinones via Sequential MW-Assisted Intramolecular Friedel-Crafts Alkylation …

MC Ortiz Villamizar, CE Puerto Galvis… - Molecules, 2022 - mdpi.com
A rapid, efficient, and original synthesis of novel pyrido [3, 2, 1-de] phenanthridin-6-ones is
reported. First, the key cinnamamide intermediates 8a–f were easily prepared from …

Перспективные точки роста и вызовы фторорганической химии

ЛВ Политанская, ГА Селиванова, ЕВ Пантелеева… - Успехи химии, 2019 - mathnet.ru
В настоящее время химия фторорганических соединений является одной из
лидирующих и быстро прогрессирующих областей органической химии. Наличие в …