Benzo-fused γ-lactam rings such as isoindolin-2-ones and 2-oxindoles are part of the
structure of many pharmaceutically active molecules. They can be often synthesized by …

Unprecedented enantioselective intramolecular Heck carbonylation reactions of
arenediazonium salts were enabled by a chiral N, N ligand. This reaction constitutes the first …

The chemistry of palladium complexes has no limits. Many domino processes (even
multicomponent) are continuously appearing in the literature. Carbocyclic and heterocyclic …

Benzo-fused γ-lactams are fundamental in medicinal chemistry, acting as essential elements
for various therapeutic agents due to their structural adaptability and capability to enhance …

Sternbach-Reeder rearrangement of 2-chloromethyl substituted derivatives of
benzimidazolo annulated analog of quinazoline 4 (ae) with propargyl amine (5) proceeded …

A Pd-catalyzed intramolecular cyclization–thiocarbonylation cascade using thioesters is
described. The developed cascade reaction afforded chromane, coumaran, indoline, and …

Designer benzodiazepines have recently appeared in many forensic cases as legal
alternatives to federally scheduled drugs such as diazepam (Valium) and alprazolam …

We have developed a palladium-catalyzed thiocarbonylation through the reaction of a σ-
alkyl palladium intermediate with carbon monoxide and a triisopropylsilyl (TIPS) thioether …

Abstract The Suzuki-Miyaura cross-coupling reaction using 4-amino-1, 2, 4-triazoles and 1,
3, 4-oxadiazoles-2-thiones· palladium (II) is studied. The reaction is optimized and the most …