Homogeneous and heterogeneous catalytic reduction of amides and related compounds using molecular hydrogen

JR Cabrero-Antonino, R Adam, V Papa… - Nature …, 2020 - nature.com
Catalytic hydrogenation of amides is of great interest for chemists working in organic
synthesis, as the resulting amines are widely featured in natural products, drugs …

Trends in the usage of bidentate phosphines as ligands in nickel catalysis

AL Clevenger, RM Stolley, J Aderibigbe… - Chemical …, 2020 - ACS Publications
A critically important process in catalysis is the formation of an active catalyst from the
combination of a metal precursor and a ligand, as the efficacy of this reaction governs the …

[HTML][HTML] Synthesis of ruthenium complexes and their catalytic applications: A review

J Hafeez, M Bilal, N Rasool, U Hafeez… - Arabian Journal of …, 2022 - Elsevier
Ruthenium complexes are an important class that has multiple catalytic and biological
applications. Ruthenium has a remarkably broad and diversified chemical spectrum. In the …

Molecularly defined manganese catalyst for low-temperature hydrogenation of carbon monoxide to methanol

P Ryabchuk, K Stier, K Junge… - Journal of the …, 2019 - ACS Publications
Methanol synthesis from syngas (CO/H2 mixtures) is one of the largest manmade chemical
processes with annual production reaching 100 million tons. The current industrial method …

Highly efficient hydrogenation of carbamates catalyzed by pincer ruthenium complexes

Z Wang, X Yan, N Ma, S Liu, P Han, H Li, Q Mahmood… - Journal of …, 2023 - Elsevier
Abstract The [fac-PNN] RuH (PPh 3)(CO) complex (Ru1) has been identified as a highly
efficient catalyst for the hydrogenation of a broad spectrum of arylcarbamates and their …

La[N(SiMe3)2]3-Catalyzed Ester Reductions with Pinacolborane: Scope and Mechanism of Ester Cleavage

CJ Barger, A Motta, VL Weidner, TL Lohr… - ACS Catalysis, 2019 - ACS Publications
Tris [N, N-bis (trimethylsilyl) amido] lanthanum (LaNTMS) is an efficient, highly active, and
selective homogeneous catalyst for ester reduction with pinacolborane (HBpin). Alkyl and …

Selective room-temperature hydrogenation of amides to amines and alcohols catalyzed by a ruthenium pincer complex and mechanistic insight

S Kar, M Rauch, A Kumar, G Leitus, Y Ben-David… - ACS …, 2020 - ACS Publications
We report a room-temperature protocol for the hydrogenation of various amides to produce
amines and alcohols. Compared with most previous reports for this transformation, which …

Catalytic Reductive Alcohol Etherifications with Carbonyl‐Based Compounds or CO2 and Related Transformations for the Synthesis of Ether Derivatives

C Lluna‐Galán, L Izquierdo‐Aranda, R Adam… - …, 2021 - Wiley Online Library
Ether derivatives have myriad applications in several areas of chemical industry and
academia. Hence, the development of more effective and sustainable protocols for their …

The Investigation of a Switchable Iridium Catalyst for the Hydrogenation of Amides: A Case Study of C–O Versus C–N Bond Scission

AK Ravn, NM Rezayee - ACS Catalysis, 2022 - ACS Publications
This Letter studies a switchable Cp*-iridium catalyst supported by a 1, 10-phenanthroline-2,
9-diol (Cp*= pentamethylcyclopentadienyl) for the hydrogenation of amides. Depending on …

Cobalt‐Catalyzed Selective Transformation of Levulinic Acid and Amines into Pyrrolidines and Pyrrolidinones using Hydrogen

Y Pan, Z Luo, J Yang, J Han, J Yang… - Advanced Synthesis …, 2022 - Wiley Online Library
Cobalt‐catalyzed selective transformation of levulinic acid and primary amines into
pyrrolidines and pyrrolidinones under H2 has been developed. The catalyst system …