This article sets out to review the chemistry relating to the synthesis of structural and
functional analogues of the three classes of hydrogenases. This chemistry has grown …

Main-group element-bridged transition metal carbonyl complexes represent an important
field in contemporary chemistry. This review will focus on the recent development of groups …

Bioorganometallic chemistry's beginnings 25 years ago were timid, modest and sporadic,
overshadowed by the supremacy of organometallic catalysis at that time. Its development …

A new synthetic method for annulating hydroquinones to Fe2S2 (CO) 6 moieties is reported.
Piperidine catalyzed a multistep reaction between Fe2 (μ-SH) 2 (CO) 6 and quinones to …

Publisher Summary The chemistry of transition metal–chalcogenide clusters has been
widely explored. In some clusters, the behavior of selenium can be different from that of both …

Rare examples of (μ-η2: η2-disulfido) dicopper complexes have been prepared from Cu (I)
and Cu (II) complexes of β-diketiminate and anilido− imine supporting ligands. A novel …

Reaction of [Cp* MoCl4], 1 (Cp*= η5-C5Me5), with [LiBH4· thf] in toluene at− 70° C, followed
by pyrolysis with excess dichalcogenides RE-ER (R= Ph, CH2Ph, 2, 6-(tBu) 2 …

To learn from Nature how to create an efficient hydrogen‐producing catalyst, much attention
has been paid to the investigation of structural and functional biomimics of the active site of …

The reaction of Mn2 (CO) 7 (μ-S2)(1) with [CpMo (CO) 3] 2 (Cp= C5H5) and [Cp* Mo (CO) 3]
2 (Cp*= C5 (CH3) 5) yielded the new mixed-metal disulfide complexes CpMoMn (CO) 5 (μ …

Four new dicobalt–iron cluster complexes with bridging or chelating diphosphine ligands
have been prepared and structurally characterized. Treatment of (μ 3-S) FeCo 2 (CO) 9 (A) …