Due to their atomically precise structures and intriguing chemical/physical properties, metal
nanoclusters are an emerging class of modular nanomaterials. Photo-luminescence (PL) is …

Stimuli-responsive functional materials with specific properties have been garnering recent
attention. Various external stimulations, such as light, mechanical or pressure, vapor, solvent …

The first methodology for Au (I/III)-catalyzed oxidative cross-coupling of arenes via double C–
H activation has been developed. The reaction is fully selective for the cross-coupling …

Medicinal applications of gold complexes have recently attracted attention due to their
innovative antitumor mechanisms. In this work, two hypercoordinated carbon-centered gold …

Electroluminescent (EL) clusters emerged rapidly, owing to their organic–inorganic hybrid
character useful for comprehensive performance integration and the potential for large …

Self‐assembly of metavanadate and organosilver (I) salts leads to a novel dodecahedrane‐
like [Ag30 (tBuS) 20] 10+ silver (I) thiolate nanocage that tightly wraps an unusual C2h …

The cyanomethyl radical was easily generated from acetonitrile by using DTBP, which was
applied to a cascade alkene addition and cyclization reaction to construct useful oxindole …

The general method for the oxidative cyclization of arylacrylamides with dichloromethane or
acetonitrile has been developed. The reactions described provide novel access to chloro …

Gold clusters have attracted great interest for a long time, and homo and heterometallic gold
clusters with hypercoordinated carbon are particularly interesting. This is due to their novel …

A polyoxometalate-templated silver thiolate nanocluster,[Ag62 (StBu) 40
(Mo20O66)(Mo6O19) 3 (CH3CN) 2]·(CF3SO3) 4 (1), has been isolated, in which a giant …