While the implication of the aromaticity concept has been dramatically expanded to date
since its emergence in 1865, the classical [4n+ 2]/4n-electron counting protocol still plays an …

This review describes synthetic concepts and breakthroughs in 1, 4-diphosphinine and
related P-bridged bis (NHCs) chemistry, covering the last four decades, starting from …

Luminescent CuI complexes have attracted significant interest due to their adjustable
emission properties, diverse structures, and reasonable cost. In this work, two class of …

We report the substitution of λ5-phosphinines (2, 6-dicarbonitrile diphenyl-1-λ5-
phosphinine) with an amino group. The impact of these modifications on both the optical and …

In the context of materials science, six-membered phosphorus heterocycles are intriguing
building blocks due to their tunable properties through phosphorus post-functionalization …

Structure and reactivity of novel Ag (I) complexes with tridentate phosphinine
(phosphabenzene) ligands are discussed in this article. An equilibrium between the dimer …

Stable planar dithienoarsinines were synthesized and structurally characterized. These
compounds exhibit monomeric structures in the solution and solid states, avoiding …

Anionic 1, 4-dihydro-1, 4-diphosphinines were synthesized from tricyclic 1, 4-diphosphinines
and isolated as blue powdery salts M [2a–2c]. Reaction of solutions of these monoanions …

A synthetic strategy toward phosphahelicenes containing a terminal phosphinine ring has
been explored. The 4-phenyl-6-methyl-2-phospha [7] helicene was prepared from starting 2 …

Tetrapyridyl-functionalized phosphinines were prepared and structurally characterized. The
donor-functionalized aromatic phosphorus heterocycles react highly selectively and even …