Recent advances in radical difunctionalization of simple alkenes

XW Lan, NX Wang, Y Xing - European Journal of Organic …, 2017 - Wiley Online Library
Direct difunctionalization of simple alkenes, the incorporation of two functional groups onto a
carbon–carbon double bond, is of particular interest to the chemical community owing to its …

[HTML][HTML] Interfacing graphene-based materials with neural cells

M Bramini, G Alberini, E Colombo… - Frontiers in systems …, 2018 - frontiersin.org
The scientific community has witnessed an exponential increase in the applications of
graphene and graphene-based materials in a wide range of fields, from engineering to …

Visible light-mediated radical-cascade addition/cyclization of arylacrylamides with aldehydes to form quaternary oxindoles at room temperature

Z Sun, H Huang, Q Wang, C Huang, G Mao… - Organic Chemistry …, 2022 - pubs.rsc.org
A visible-light-mediated oxidative cyclization of N-arylacrylamides by a radical cascade with
readily available aliphatic or aromatic aldehydes was achieved. This transformation …

Csp3–Csp2 Coupling of Isonitriles and (Hetero)arenes through a Photoredox-Catalyzed Double Decyanation Process

M Martín, RM Romero, C Portolani, M Tortosa - ACS catalysis, 2024 - ACS Publications
Herein, we demonstrate the ability of isonitriles to be used as alkyl radical precursors in a
photoredox-catalyzed transformation involving selective C–N cleavage and Csp3–Csp2 …

Redox-Neutral Radical Cascade Cyclization of N-Arylacrylamides with Unactivated Alkyl and Aryl Chlorides

AK Jha, DP Nair, M Arif, GS Yedase… - The Journal of …, 2023 - ACS Publications
Herein, we report the first metal-free, redox-neutral strategy for radical cascade alkylative
radical addition, cyclization of N-arylacrylamides with unactivated alkyl chlorides to give …

Photoinduced efficient synthesis of cyanoalkylsulfonylated oxindoles via sulfur dioxide insertion

F Teng, J Du, C Xun, M Zhu, Z Lu, H Jiang… - Organic & …, 2021 - pubs.rsc.org
A visible-light-promoted radical cascade reaction of N-arylacrylamide and cyclobutanone
oxime esters with sulfur dioxide insertion is established. Mainly through the exploration of …

Donor–Acceptor Complex Enables Cascade Radical Cyclization of N-Arylacrylamides with Katritzky Salts

Y Lu, CZ Fang, Q Liu, BL Li, ZX Wang, XY Chen - Organic Letters, 2021 - ACS Publications
Cascade radical cyclization of N-arylacrylamides is an attractive method to prepare 3, 3-
disubstituted oxindoles. As the reported methods often require additives and/or …

Steering Site‐Selectivity in Transition Metal‐Catalyzed C− H Bond Functionalization: the Challenge of Benzanilides

R Gramage‐Doria - Chemistry–A European Journal, 2020 - Wiley Online Library
Selective C− H bond functionalization catalyzed by metal complexes have completely
revolutionized the way in which chemical synthesis is conceived nowadays. Typically, the …

Nickel-catalyzed transformation of diazoacetates to alkyl radicals using alcohol as a hydrogen source

J Zhao, P Li, Y Xu, Y Shi, F Li - Organic letters, 2019 - ACS Publications
A nickel-catalyzed transformation of diazoacetates to α-carbonyl methylene radicals has
been disclosed in the presence of hyperoxide using ethanol as a hydrogen source and …

Rhenium-catalyzed alkylarylation of alkenes with PhI (O 2 CR) 2 via decarboxylation to access indolinones and dihydroquinolinones

L Zhang, Y Wang, Y Yang, P Zhang… - Organic Chemistry …, 2020 - pubs.rsc.org
Rhenium-catalyzed alkylarylation of alkenes with hypervalent iodine (III) reagents (HIRs) via
decarboxylation to access various 3, 3-disubstituted indolinones and trans-3, 4 …