Recent developments in the preparation and chemistry of metallacycles and metallacages via coordination

TR Cook, PJ Stang - Chemical reviews, 2015 - ACS Publications
The continued development of molecular architectures of consequence to both longstanding
and newly recognized problems demands ever evolving synthetic routes, characterizations …

Spin crossover in discrete polynuclear iron (II) complexes

RW Hogue, S Singh, S Brooker - Chemical Society Reviews, 2018 - pubs.rsc.org
Iron (II) spin crossover (SCO) materials have been widely studied as molecular switches with
a wide variety of potential applications, including as displays, sensors, actuators or memory …

Heterometallic cages: synthesis and applications

LK Moree, LAV Faulkner, JD Crowley - Chemical Society Reviews, 2024 - pubs.rsc.org
High symmetry metallosupramolecular architectures (MSAs) have been exploited for a
range of applications including molecular recognition, catalysis and drug delivery. Recently …

Spin crossover with thermal hysteresis: practicalities and lessons learnt

S Brooker - Chemical Society Reviews, 2015 - pubs.rsc.org
The observation of spin crossover with thermal hysteresis loops of more than a few Kelvin
remains relatively uncommon and unpredictable, so is a relatively underdeveloped, but …

Imidazole-based metal-organic cages: Synthesis, structures, and functions

XW Zhu, D Luo, XP Zhou, D Li - Coordination Chemistry Reviews, 2022 - Elsevier
The coordination-driven self-assembly provides a favourable methodology for constructing
metal–organic architectures with diverse structures and functions. As a classical five …

Controlling dynamic magnetic properties of coordination clusters via switchable electronic configuration

W Huang, X Ma, O Sato, D Wu - Chemical Society Reviews, 2021 - pubs.rsc.org
Large-sized coordination clusters have emerged as a new class of molecular materials in
which many metal atoms and organic ligands are integrated to synergize their properties. As …

54 K Spin Transition Temperature Shift in a Fe6L4 Octahedral Cage Induced by Optimal Fitted Multiple Guests

F Yin, J Yang, LP Zhou, X Meng, CB Tian… - Journal of the …, 2024 - ACS Publications
Spin-crossover (SCO) coordination cages are at the forefront of research for their potential in
crafting next-generation molecular devices. However, due to the scarcity of SCO hosts and …

Crystalline central-metal transformation in metal-organic frameworks

H Wang, W Meng, J Wu, J Ding, H Hou… - Coordination Chemistry …, 2016 - Elsevier
Recently, there has been considerable interest in the transformation of metal nodes in metal-
organic frameworks (MOFs) because this transformation can yield favorable changes in their …

Spin crossover in homoleptic Fe (II) imidazolylimine complexes

HS Scott, RW Staniland, PE Kruger - Coordination Chemistry Reviews, 2018 - Elsevier
The straightforward synthesis of a diverse variety of imidazolylimine ligands has led to the
preparation of a large number of molecular iron (II) complexes, many of which undergo spin …

'Click'to functionalise: synthesis, characterisation and enhancement of the physical properties of a series of exo-and endo-functionalised Pd 2 L 4 nanocages

JEM Lewis, ABS Elliott, CJ McAdam, KC Gordon… - Chemical …, 2014 - pubs.rsc.org
The synthesis of self-assembled metallosupramolecular architectures has been of steadily
growing interest in recent years due to their diverse applications. Appending additional …