Laser probes of conformational isomerization in flexible molecules and complexes

TS Zwier - The Journal of Physical Chemistry A, 2006 - ACS Publications
Molecules with several flexible coordinates have potential energy surfaces with a large
number of minima and many transition states separating them. A general experimental …

Rotationally resolved B̃←X̃ electronic spectra of the isopropoxy radical: A comparative study

J Liu, D Melnik, TA Miller - The Journal of chemical physics, 2013 - pubs.aip.org
Rotationally resolved |${\tilde{B}} \leftarrow {\tilde{X}}$|B̃←X̃ electronic spectra of the isopropoxy
radical: A comparative study | The Journal of Chemical Physics | AIP Publishing Skip to Main …

[HTML][HTML] Electronic spectroscopy of the A1̃2A′′/A2̃2A′− X̃2A′ transitions of jet-cooled calcium ethoxide radicals: Vibronic structure of alkaline earth monoalkoxide …

AC Paul, K Sharma, H Telfah, TA Miller… - The Journal of Chemical …, 2021 - pubs.aip.org
Laser-induced fluorescence/dispersed fluorescence (LIF/DF) and cavity ring-down spectra
of the A 1 ̃ 2 A′′/A 2 ̃ 2 A′− X ̃ 2 A′ electronic transition of the calcium ethoxide (CaOC 2 …

CH3O Substitution Effect Revisited in the Vibrationally Resolved Laser-Induced Fluorescence Spectra of Methoxycyclohexoxy Radicals

Y Zou, F Yu, X Liu, L Zu - The Journal of Physical Chemistry A, 2024 - ACS Publications
The oxy-substituted alkoxy radicals have attracted wide attention due to the increasing
application of oxygenated volatile organic compounds as fuel additives and solvents. Direct …

A combined experimental and computational study on the transition of the calcium isopropoxide radical as a candidate for direct laser cooling

H Telfah, K Sharma, AC Paul, SMS Riyadh… - Physical Chemistry …, 2022 - pubs.rsc.org
Vibronically resolved laser-induced fluorescence/dispersed fluorescence (LIF/DF) and cavity
ring-down (CRD) spectra of the electronic transition of the calcium isopropoxide [CaOCH …

Jet-cooled laser-induced fluorescence spectroscopy of cyclohexoxy: Rotational and fine structure of molecules in nearly degenerate electronic states

J Liu, TA Miller - The Journal of Physical Chemistry A, 2014 - ACS Publications
The rotational structure of the previously observed B̃ 2A′← X̃ 2A ″and B̃ 2A′← Ã 2A′
laser-induced fluorescence spectra of jet-cooled cyclohexoxy radical (c-C6H11O)[Zu, L.; Liu …

Unified Description of the Jahn–Teller Effect in Molecules with Only Cs Symmetry: Cyclohexoxy in Its Full 48-Dimensional Internal Coordinates

Y Shen, DR Yarkony - The Journal of Physical Chemistry A, 2021 - ACS Publications
The two lowest potential energy surfaces of cyclohexoxy which are coupled by conical
intersections and the spin–orbit interaction are determined in the full 48-dimensional internal …

[HTML][HTML] Rotational and fine structure of open-shell molecules in nearly degenerate electronic states

J Liu - The Journal of Chemical Physics, 2018 - pubs.aip.org
An effective Hamiltonian without symmetry restriction has been developed to model the
rotational and fine structure of two nearly degenerate electronic states of an open-shell …

Ground and excited state infrared spectroscopy of jet-cooled radicals: Exploring the photophysics of trihydronaphthyl and inden-2-ylmethyl

NM Kidwell, DN Mehta-Hurt, JA Korn… - The Journal of …, 2014 - pubs.aip.org
The alkyl and aromatic CH stretch infrared spectra of inden-2-ylmethyl (I2M, C 10 H 9) and
trihydronaphthyl (THN, C 10 H 11) radicals have been recorded under jet-cooled conditions …

On the thermal unimolecular decomposition of the cyclohexoxy radical—an experimental and theoretical study

O Welz, F Striebel, M Olzmann - Physical Chemistry Chemical Physics, 2008 - pubs.rsc.org
The kinetics of the thermal unimolecular decomposition of the cyclohexoxy radical (c-
C6H11O) was experimentally studied, and the results were analyzed in terms of statistical …