Catalytic reactions in ionic liquids (ILs) have been examined for at least 20 years; for example, the first report of the use of an IL as a catalyst in Friedel-Crafts acylation was …
Ionic liquids are becoming widely used in synthetic organic chemistry and yet relatively little attention has been paid to the intrinsic reactivity of these low temperature molten salts. Clues …
JW Lee, JY Shin, YS Chun, HB Jang… - Accounts of chemical …, 2010 - ACS Publications
Over the past decade, ionic liquids have received a great deal of attention as a new means for catalyst immobilization. Large numbers of catalysts having polar or ionic character have …
L Crowhurst, NL Lancaster… - Journal of the …, 2004 - ACS Publications
In this work we report the effect of ionic liquids on a class of charge-neutral nucleophiles. We have studied the reactions of nbutylamine, di-nbutylamine, and tri-nbutylamine with methyl p …
NS Shaikh, K Junge, M Beller - Organic Letters, 2007 - ACS Publications
A general and highly chemoselective hydrosilylation of aldehydes using iron catalysts is reported. Fe (OAc) 2 in the presence of tricyclohexylphosphine as ligand and …
J Pavlinac, M Zupan, KK Laali, S Stavber - Tetrahedron, 2009 - Elsevier
The term ionic liquid (IL) generally refers to salts with a melting temperature below the boiling point of water. Although considerable interest has been shown in ILs in the last …
SS Shinde, BS Lee, DY Chi - Organic letters, 2008 - ACS Publications
We have demonstrated the synergistic effect in nucleophilic fluorination when we combined two solvents ionic liquid (IL) and tert-alcohol into one molecule. Consequently, these …
D Fang, J Cheng, K Gong, QR Shi, XL Zhou… - Journal of Fluorine …, 2008 - Elsevier
A green and novel procedure is described for the preparation of a series of ionic liquid containing alkylimidazolium-based or N-alkylpyridinium-based cations and …