While the implication of the aromaticity concept has been dramatically expanded to date
since its emergence in 1865, the classical [4n+ 2]/4n-electron counting protocol still plays an …

Homoleptic cyanide compounds exist of almost all main group elements. While the alkali
metals and alkaline earth metals form cyanide salts, the cyanides of the lighter main group …

A comprehensive reactivity study of gallapnictenes LGaEGa (Cl) L (E= As, Sb; L= HC [C
(Me) N (Ar)] 2, Ar= Dip= 2, 6‐i‐Pr2C6H3) proved the nucleophilic character of the pnictogen …

A convenient synthesis of dicyanophosphide and dicyanoarsenide anions is reported.
These heavy homologues of the long‐known and fundamentally important dicyanamide …

Abstract Erste systematische Studien zur Reaktivität von Gallapnictenen LGaEGa (Cl) L (E=
As, Sb; L= HC [C (Me) N (Ar)] 2, Ar= Dip= 2, 6‐i‐Pr2C6H3) zeigen den nukleophilen …

When [PPN] SCN (1; PPN=[Ph3P–N–PPh3]) is treated with Me3Si–SCN in
methanol,[PPN][H (NCS) 2](2), a hydrogen diisothiocyanate salt bearing the [H (NCS) 2] …

The cyaphide anion, CP−, is shown to undergo three distinct oligomerization reactions in the
coordination sphere of metals. Reductive coupling of Au (IDipp)(CP)(IDipp= 1, 3‐bis (2, 6 …

Abstract N, N′, N′′, N′′′, N′′′′, N′′′′′‐(Triphenylene‐2, 3, 6, 7, 10, 11‐
hexayl) hexapicolinamide (H6hptp), a triangular ligand containing three noninnocent …

Within the second funding period of the SPP 1708 “Material Synthesis near Room
Temperature”, which started in 2017, we were able to synthesize novel anionic species …

Anionic phosphorus and arsenic compounds have found numerous uses as building blocks
in synthetic main group chemistry. In particular, phosphanides and arsanides ([RER']−, E= P …