Metal–organic cages (MOCs) are discrete, supramolecular entities that consist of metal
nodes and organic linkers, which can offer solution processability and high porosity …

The continued development of molecular architectures of consequence to both longstanding
and newly recognized problems demands ever evolving synthetic routes, characterizations …

In this review, a comprehensive summary of supramolecular transformations within discrete
coordination-driven supramolecular architectures, including helices, metallacycles …

A growing variety of covalent reactions have been employed to achieve the post-assembly
modification (PAM) of self-assembled metallosupramolecular complexes. Covalent PAM …

The anthracene panels of two tetrahedral MII4L6 cages, where MII= CoII or FeII, were found
to react with photogenerated singlet oxygen (1O2) in a hetero‐Diels–Alder reaction. ESI‐MS …

Here we demonstrate how the hydrogen-bonding ability of a BINOL-based dialdehyde
subcomponent dictated the stereochemical outcome of its subsequent self-assembly into …

Self-assembly of a carboxylic acid-containing ligand into an Fe4L6 iminopyridine cage
allows endohedral positioning of the acid groups while maintaining a robust cage structure …

Natural reaction cascades control the movement of biomolecules between cellular
compartments. Inspired by these systems, we report a synthetic reaction cascade employing …

The combination of a bent diamino (nickel (II) porphyrin) with 2‐formylpyridine and FeII
yielded an FeII4L6 cage. Upon treatment with the fullerenes C60 or C70, this cage was …

The cavities of artificial receptors are defined by how their components fit together. The
encapsulation of specific molecules can thus be engineered by considering geometric …