Stable Two-Coordinate, Open-Shell (d1–d9) Transition Metal Complexes
PP Power - Chemical Reviews, 2012 - ACS Publications
1. INTRODUCTION Stable, open-shell (d1− d9) transition metal complexes in which the
metal is two-coordinate or quasi-two-coordinate are among the rarest and least investigated …
metal is two-coordinate or quasi-two-coordinate are among the rarest and least investigated …
Element derivatives of sterically encumbering terphenyl ligands
B Twamley, ST Haubrich, PP Power - Advances in organometallic …, 1999 - Elsevier
Publisher Summary The use of sterically crowding ligands to manipulate reactivity and to
effect the stabilization of previously unknown bonding types, geometries, or electron …
effect the stabilization of previously unknown bonding types, geometries, or electron …
Single-Site β-Diiminate Zinc Catalysts for the Alternating Copolymerization of CO2 and Epoxides: Catalyst Synthesis and Unprecedented Polymerization Activity
Synthetic routes to zinc β-diiminate complexes are reported. The synthesis of 11 β-diimine
[(BDI)-H] ligands, with varying N-aryl substituents and bridging structures, is described …
[(BDI)-H] ligands, with varying N-aryl substituents and bridging structures, is described …
Comparative study of the coordination chemistry and lactide polymerization of alkoxide and amide complexes of zinc and magnesium with a β-diiminato ligand …
MH Chisholm, JC Gallucci, K Phomphrai - Inorganic chemistry, 2005 - ACS Publications
A series of β-diiminato complexes of the form (BDI-3) MX where (BDI-3)=[CH (CMeNC6H4-2-
OMe) 2]; M= Zn, Mg; X= O i Pr, O t Bu, or N (SiMe3) 2 has been synthesized. The (BDI-3) …
OMe) 2]; M= Zn, Mg; X= O i Pr, O t Bu, or N (SiMe3) 2 has been synthesized. The (BDI-3) …
Dispersion forces and counterintuitive steric effects in main group molecules: heavier group 14 (Si–Pb) dichalcogenolate carbene analogues with sub-90° interligand …
BD Rekken, TM Brown, JC Fettinger… - Journal of the …, 2013 - ACS Publications
The synthesis and spectroscopic and structural characterization of an extensive series of
acyclic, monomeric tetrylene dichalcogenolates of formula M (ChAr) 2 (M= Si, Ge, Sn, Pb; …
acyclic, monomeric tetrylene dichalcogenolates of formula M (ChAr) 2 (M= Si, Ge, Sn, Pb; …
Hydrolysis and Transfer Reactivity of the Coordinated Thiolate, Thiocarboxylate, and Selenolate in Binuclear Zinc (II) Complexes
AB Chakraborty, T Ganguly, A Majumdar - Inorganic Chemistry, 2023 - ACS Publications
A new binuclear Zn (II) complex,[Zn2 (PhBIMP)(DMF) 2] 3+(1)(where PhBIMP1 is the anion
of 2, 6-bis [bis [(N-1-methyl-4, 5-diphenylimidazoylmethyl) amino] methyl]-4-methylphenol) …
of 2, 6-bis [bis [(N-1-methyl-4, 5-diphenylimidazoylmethyl) amino] methyl]-4-methylphenol) …
Enabling computational design of ZIFs using ReaxFF
Classical force fields have been broadly used in studies of metal–organic framework
crystals. However, processes involving bond breaking or forming are prohibited due to the …
crystals. However, processes involving bond breaking or forming are prohibited due to the …
Synthesis of sterically encumbered terphenyls and characterization of their metal derivatives Et2OLiC6H3-2, 6-Trip2 and Me2SCuC6H3-2, 6-Trip2 (Trip= 2, 4, 6-i …
B Schiemenz, PP Power - Organometallics, 1996 - ACS Publications
The synthesis and characterization of sterically encumbered terphenyl compounds are
described. These are 2, 6-Dipp2C6H3I (Dipp= 2, 6-i-Pr2C6H3-), 1, 2, 6-Trip2C6H3I (Trip= 2 …
described. These are 2, 6-Dipp2C6H3I (Dipp= 2, 6-i-Pr2C6H3-), 1, 2, 6-Trip2C6H3I (Trip= 2 …
A Zinc–Zinc‐Bonded Compound and Its Derivatives Bridged by One or Two Hydrogen Atoms: A New Type of Zn Zn Bonding
Z Zhu, RJ Wright, MM Olmstead, E Rivard… - Angewandte …, 2006 - Wiley Online Library
Recently, the synthesis and structural characterization of decamethyldizincocene [Cp*
ZnZnCp*](1; Cp*= η5-C5Me5, ZnÀZn 2.305 (3)) was reported by Carmona and co …
ZnZnCp*](1; Cp*= η5-C5Me5, ZnÀZn 2.305 (3)) was reported by Carmona and co …
Synthesis and Characterization of a Two‐Coordinate Manganese Complex and its Reaction with Molecular Hydrogen at Room Temperature
In 2005 we reported the first LMnÀMnL compound (L= CH (CMeNAr) 2, Ar= 2, 6-iPr2C6H3)
obtained by the reduction of LMnCl with sodium–potassium alloy. The resulting compound …
obtained by the reduction of LMnCl with sodium–potassium alloy. The resulting compound …