Recently, the research activity in the field of the stereospecific polymerization of conjugated
dienes has focused on the use of catalysts based on organometallic complexes having a …

Aluminum-based transition-metal-free catalysts for α-olefin polymerization have garnered
extensive research interest from academia and industries over the past two decades …

Dichloro (2, 2′-bipyridine) copper was synthesized by reacting copper dichloride with
bypyridine, and its behavior, in combination with methylaluminoxane (MAO), in the …

A series of vanadium (III) complexes containing diphosphine ligands of the type R 2 P (CH
2) 2 PR 2 [R= Me (dmpe, 1a), R= Et (depe, 1b), R= Ph (dppe, 1c)] were synthesized by …

Stereoregular polymerizations are of high importance, which disclosing the relationships
between microstructures and physical properties of polymers. In this contribution, a series of …

Herein, we report the homo-and co-polymerization of ethylene (E) with norbornene (NB)
catalyzed by vanadium (III) phosphine complexes of the type VCl3 (PMenPh3-n) 2 [n= 2 …

A series of vanadium complexes bearing iminopyridine bidentate ligands with various
electronic and steric properties: V1 [CH2Ph], V2 [CMe2CH2CMe3], V3 [Ph] and V4 [2, 6-i …

1. Background Since its first discovery at the beginning of the 1960s [1], the coordinative
polymerization of conjugated dienes has improved continuously, performer better and better …

We have designed new hydroborane fullerene-based pincer ligands of BH-(NCH 2 PR 2) 2
C 60, R= H, CH 3, tBu and Ph, and their metal complexes. It is found that the substitution of …

В данной статье обобщены основные тенденции, особенно, за последние пять лет по
полимеризации бутадиена и функционализации полученного полибутадиена. Главной …