Photoinduced organocatalyzed atom transfer radical polymerization (O-ATRP): precision polymer synthesis using organic photoredox catalysis

DA Corbin, GM Miyake - Chemical reviews, 2021 - ACS Publications
The development of photoinduced organocatalyzed atom transfer radical polymerization (O-
ATRP) has received considerable attention since its introduction in 2014. Expanding on …

Rate coefficients of free-radical polymerization deduced from pulsed laser experiments

S Beuermann, M Buback - Progress in Polymer Science, 2002 - Elsevier
Pulsed laser techniques have enormously improved the quality by which rate coefficients of
individual steps in free-radical polymerization may be measured. Pulsed laser initiated …

Critically evaluated rate coefficients for free‐radical polymerization, 1. Propagation rate coefficient for styrene

M Buback, RG Gilbert, RA Hutchinson… - Macromolecular …, 1995 - Wiley Online Library
Pulsed‐laser polymerization (PLP) in conjugation with molecular weight distribution (MWD)
measurement has emerged as the method of choice for determining the propagation rate …

Critically evaluated rate coefficients for free‐radical polymerization, 2.. Propagation rate coefficients for methyl methacrylate

S Beuermann, M Buback, TP Davis… - Macromolecular …, 1997 - Wiley Online Library
Pulsed‐laser polymerization (PLP) in conjunction with molar mass distribution (MMD)
measurement is the method of choice for determining the propagation rate coefficient kp in …

Catalytic chain transfer in free-radical polymerizations

AA Gridnev, SD Ittel - Chemical Reviews, 2001 - ACS Publications
While free-radical chain reactions were known shortly after the turn of the 20th century, it
was not until the mid-1930s that free-radical polymerization was recognized. Today, free …

Determination of free-radical propagation rate coefficients of butyl, 2-ethylhexyl, and dodecyl acrylates by pulsed-laser polymerization

S Beuermann, DA Paquet, JH McMinn… - …, 1996 - ACS Publications
Analysis of the molecular weight distributions (MWDs) of polymer produced by pulsed-laser
polymerization (PLP) is an effective method for the determination of free-radical propagation …

Update and critical reanalysis of IUPAC benchmark propagation rate coefficient data

S Beuermann, S Harrisson, RA Hutchinson… - Polymer …, 2022 - pubs.rsc.org
We present an updated and expanded dataset of benchmark propagation rate coefficient
(kp) data obtained from pulsed laser polymerization (PLP) of 13 vinyl monomers (styrene …

Effect of initiation conditions on the uniformity of three-arm star molecular brushes

K Matyjaszewski, S Qin, JR Boyce… - …, 2003 - ACS Publications
A series of three-arm star densely grafted molecular brushes with poly (n-butyl acrylate) side
chains were prepared by atom transfer radical polymerization (ATRP). The three-arm …

Chain transfer activity of ω-unsaturated methyl methacrylate oligomers

CL Moad, G Moad, E Rizzardo, SH Thang - Macromolecules, 1996 - ACS Publications
The chain transfer activities of a series of ω-unsaturated methyl methacrylate oligomers
[(dimer (1), trimer (2), tetramer (3), and a methyl methacrylate macromonomer with average …

Controlled Radical Polymerization of (Meth)acrylates by ATRP with NiBr2(PPh3)2 as Catalyst

G Moineau, M Minet, P Dubois, P Teyssie… - …, 1999 - ACS Publications
NiBr2 (PPh3) 2 has been found to be an efficient catalyst for the ATRP of methyl
methacrylate (MMA) and n-butyl acrylate (n-BuA) initiated by an alkyl halide in the absence …