Carbon− heteroatom bond formations are very important reactions in organic synthesis and
have attracted the interest of many synthetic organic chemists, leading them to develop new …

Enantioselective proton transfer refers to the process of enantioselective introduction of
protons to carbanions through the recognition of prochiral faces. Enantioselective proton …

The highly enantioselective sulfa-Michael addition of alkyl thiols to unactivated α-substituted
acrylate esters catalyzed by a bifunctional iminophosphorane organocatalyst under mild …

The highly enantioselective sulfa-Michael addition of alkyl thiols to unactivated β-substituted-
α, β-unsaturated esters catalyzed by a bifunctional iminophosphorane (BIMP) …

The first enantioselective sulfa-Michael addition of alkyl thiols to alkenyl benzimidazoles,
enabled by a bifunctional iminophosphorane (BIMP) organocatalyst, is described. The …

An enantioselective bifunctional squaramide‐catalyzed detrifluoroacetylative alkylation
reaction has been developed under electrochemical conditions. The unified strategy based …

Enantioselective protonation by hydrophosphinylation of diarylphosphine oxides with 2‐
vinyl azaheterocycle N‐oxide derivatives was demonstrated using chiral bis (guanidino) …

Remote stereocontrolled 1, 8-addition of heteroatom nucleophiles to 6-methylene-6 H-
indoles generated in situ from 6-indolylmethanols has been developed for the first time. With …

An asymmetric organocatalysed decarboxylative protonation reaction allowed a
straightforward synthesis of α-substituted isoxazolidin-5-ones from readily available 5 …

Enantioselective protonation represents an appealing approach for the construction of
nonracemic chiral tertiary carbon centres, frequently found in a large range of bio‐relevant …