Hydrogen energy-based electrochemical energy conversion technologies offer the promise
of enabling a transition of the global energy landscape from fossil fuels to renewable energy …

The electrical double layer (EDL) plays a central role in electrochemical energy systems,
impacting charge transfer mechanisms and reaction rates. The fundamental importance of …

Hydrogen evolution on platinum is a key reaction for electrocatalysis and sustainable energy
storage, yet its pH-dependent kinetics are not fully understood. Here we present a detailed …

We present detailed measurements of the double-layer capacitance of the Pt (111)–
electrolyte interface close to the potential of zero charge (PZC) in the presence of several …

The interplay between the structure and composition of the electric double layer and the
surface charge controls the electrocatalytic activity of reactions central to decarbonization of …

Electroanalytical chemists and others are concerned not only with the application of new
and classical techniques to analytical problems, but also with the fundamental theoretical …

The electrochemistry of platinum single crystals is historically reviewed. After a brief revision
of historical results dating before the publication of the landmark experiment by J. Clavilier of …

A robust and efficient computational method for electronic structure calculations of liquid-
solid interfaces is presented. The theory employs the density functional theory and a …

The structure of a liquid water layer on Pt (111) has been studied by ab initio molecular
dynamics simulations based on periodic density functional theory calculations. First the …

The hydrogen evolution reaction (HER) constitutes one of the most important reactions in
electrochemistry because of the value of hydrogen as a vector for energy storage and …