Recent advances in transition-metal-catalyzed carbene insertion to C–H bonds

Y He, Z Huang, K Wu, J Ma, YG Zhou… - Chemical Society Reviews, 2022 - pubs.rsc.org
C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …

Blue-light-induced iron-catalyzed α-alkylation of ketones

MS Abdallah, N Joly, S Gaillard, A Poater… - Organic …, 2022 - ACS Publications
We report a visible-light-induced iron-catalyzed α-alkylation of ketones. The photocatalytic
system is based on the single diaminocyclopentadienone iron tricarbonyl complex. Two …

Visible-Light-Induced Trifluoromethylsulfonylation Reaction of Diazo Compounds Enabled by Manganese Catalysis

J Bai, S Li, D Qi, Z Song, B Li, L Guo, L Song… - Organic …, 2023 - ACS Publications
A visible-light-induced trifluoromethylsulfonylation reaction of diazo compounds is herein
reported. This developed synthetic method captures the relatively rare trifluoromethyl …

Recent Advances and Prospects in Manganese‐Catalyzed C− H Activation

G Anusree, PS Devi, G Anilkumar - Advanced Synthesis & …, 2024 - Wiley Online Library
C− H activation represents an interesting alternative to conventional cross‐coupling
methods, avoiding the requirement of additional steps to introduce activating groups …

Manganese (i)-catalyzed nucleophilic addition of C (sp 3)–H bonds to aldehydes

H Liu, T Tang, B Li, B Wang - Chemical Communications, 2024 - pubs.rsc.org
The C–H bond activation catalyzed by a manganese (I) complex has achieved significant
development but is limited to C (sp2)–H bonds. In this work, an efficient manganese (I) …

Photoredox catalysis leading to triazolo-quinoxalinones at room temperature: selectivity of the rate determining step

R Monreal-Corona, E Besalú, A Pla-Quintana… - Organic & …, 2022 - pubs.rsc.org
The interest in the fusion product of quinoxalinone skeletons and 1, 2, 3-triazole units has
greatly increased in recent years since they are known to be agonists of G-protein-coupled …

Blue‐Light Induced Iron‐Catalyzed Synthesis of γ, δ‐Unsaturated Ketones

N Joly, A Colella, ME Mendy, MD Mbaye… - …, 2024 - Wiley Online Library
A visible‐light‐induced iron‐catalyzed α‐alkylation of ketones with allylic and propargylic
alcohols as pro‐electrophiles is reported. The diaminocyclopentadienone iron tricarbonyl …

Blue‐Light Enhanced Iron Catalysed Hydrosilylation of Carboxamides and Carboxylic Esters at Ambient Conditions

Q Zhang, C Darcel - European Journal of Organic Chemistry, 2024 - Wiley Online Library
We report herein a blue‐light‐promoted iron‐catalyzed reduction of carboxamides and
carboxylic esters. Conducting the reaction under hydrosilylation conditions and blue light (2 …

Capturing a pentacyclic fragment‐based library derived from perophoramidine: their design, synthesis and evaluation as anticancer compounds by DNA double …

S Guha, I Yussif El‐Deeb, S Yadav… - … A European Journal, 2022 - Wiley Online Library
Herein we have reported the discovery of a pentacyclic building block comprised of fused
indole‐quinoline and piperidinone from the natural product perophoramidine as a …

Mn-Catalyzed C–C Coupling Reactions

Y Yang, C Wang - CC Cross Couplings with 3d Base Metal Catalysts, 2023 - Springer
Manganese-catalyzed C–C bond coupling reactions are such an attractive alternative tool
for the synthesis of organic functional molecules that they are gained considerable attention …