The electronic structure, spectroscopic features, and (catalytic) reactivity of complexes with
nitrogen‐centered radical ligands are described. Complexes with aminyl ([M (. NR2)]) …

Compounds that contain a late transition metal-nitrogen multiple bond represent important
reactive intermediate species in many useful organic and inorganic transformations. In order …

A sterically accessible tert-butyl-substituted dipyrrinato di-iron (II) complex [(t BuL) FeCl] 2
possessing two bridging chloride atoms was synthesized from the previously reported …

N-Heterocyclic carbene (NHC) ligands are attracting worldwide interest because of their
considerable scope and potential in coordination/organometallic chemistry, catalysis and …

The trityl-substituted bisoxazoline (TrHBOX) was prepared as a chiral analogue to a
previously reported nickel dipyrrin system capable of ring-closing amination catalysis …

Since the seminal study by Curtius on the use of alkyl azides in organic chemistry,
particularly in CĀN bond-forming reactions, these readily available compounds have been …

Rhodium (II) dicarboxylate complexes were discovered to catalyze the intramolecular
amination of unactivated primary, secondary, or tertiary aliphatic C–H bonds using aryl …

Iron (II) bromide catalyzes the transformation of aryl and vinyl azides with ketone or methyl
oxime substituents into 2, 1-benzisoxazoles, indazoles, or pyrazoles through the formation of …

This review summarizes the properties of group 9–11 metal–oxo and metal–imido
complexes, which have been either isolated or proposed as reactive intermediates in metal …

Iron (II) bromide catalyzes the transformation of ortho-substituted aryl azides into 2, 3-
disubstituted indoles through a tandem ethereal C–H bond amination [1, 2]-shift reaction …