The addition of an allylic organometallic compound to a carbonyl compound or an imine is of
great synthetic interest because in this reaction together with a new functionality (hydroxyl or …

The addition of an organometallic reagent to a carbonyl compound or an imine represents
an important process in synthetic organic chemistry because in this reaction, together with a …

During the last century, organometallic reagents prepared from main group metals, 1 such
as organolithium, organomagnesium, and organozinc compounds, have played a central …

Enantioselective allylation is a highly used organic reaction to prepare chiral homoallylic
alcohols and amines, which serve as important building blocks in the synthesis of a variety …

A regio-and stereoselective allylation of N-unsubstituted anilines has been developed that
explores aryl allenes as masked allyl synthons and a combination of Mg (OTf) 2/HFIP as an …

A highly practical and efficient asymmetric synthesis of chiral homoallylic amines by In-
mediated allylation of chiral N-tert-butanesulfinyl imines in aqueous media at room …

Here we report the application of dual nickel/photoredox catalysis to the allylation of
aliphatic, aromatic and heteroaromatic aldehydes by using commercially available reagents …

Abstract The Hosomi-Sakurai allylation is the Lewis acid-promoted carbonyl allylation with
nucleophilic allylsilanes. Since its discovery in 1976, this highly useful transformation has …

Solutions of allyl indium reagents formed in the reactions of indium with allyl bromide and
allyl iodide, respectively, in N, N-dimethylformamide, tetrahydrofuran, and water were …

Conspectus Stereoselective indium-mediated organic reactions have enjoyed tremendous
growth in the last 25 years. This is in part due to the insensitivity of allylindium to moisture …