Ionic highways from covalent assembly in highly conducting and stable anion exchange membrane fuel cells

Y Kim, Y Wang, A France-Lanord, Y Wang… - Journal of the …, 2019 - ACS Publications
A major challenge in the development of anion exchange membranes for fuel cells is the
design and synthesis of highly stable (chemically and mechanically) conducting …

Reactivity and Selectivity of the Diels–Alder Reaction of Anthracene in [Pd6L4]12+ Supramolecular Cages: A Computational Study

XR Mao, Q Wang, SP Zhuo, LP Xu - Inorganic Chemistry, 2023 - ACS Publications
The field of supramolecular metal–organic cage catalysis has grown rapidly in recent years.
However, theoretical studies regarding the reaction mechanism and reactivity and selectivity …

Design, Synthesis, and Anticancer Activity of Triptycene–Peptide Hybrids that Induce Paraptotic Cell Death in Cancer Cells

K Yamaguchi, K Yokoi, M Umezawa… - Bioconjugate …, 2022 - ACS Publications
We report on the design and synthesis of triptycene–peptide hybrids (TPHs), 5, syn-6, and
anti-6, which are conjugates of a triptycene core unit with two or three cationic KKKGG …

Diels–Alder reactions and electrophilic substitutions with atypical regioselectivity enable functionalization of terminal rings of anthracene

VN Huynh, M Leitner, A Bhattacharyya… - Communications …, 2020 - nature.com
Reversing the regioselectivity of the renowned Diels–Alder reaction by overriding the usual
thermodynamic and kinetic governing factors has always been a formidable challenge to …

Effect of symmetric and asymmetric substitution on the optoelectronic properties of 9, 10-dicyanoanthracene

F Glöcklhofer, A Rosspeintner… - … Systems Design & …, 2019 - pubs.rsc.org
A set of substituted 9, 10-dicyanoanthracenes (DCA) has been synthesized, their
photophysical and electrochemical properties in liquid solution have been characterized …

Synthesis of triptycenemonohydroquinonedibenzoquinone by comproportionation

Y Takemasa, K Nozaki - The Journal of Organic Chemistry, 2021 - ACS Publications
Triptycenetribenzoquinone (BQ) 3, where the three benzene rings of triptycene are replaced
by 1, 4-benzoquinone (BQ) rings, is known to be reduced to triptycenetrihydroquinone (HQ) …

Ligand‐Boosted Copper Catalysis for Air‐Tolerant Methoxylation of (Hetero) aryl Halides With Sodium Methoxide

K Xu, S Wu, G Zou - Applied Organometallic Chemistry, 2024 - Wiley Online Library
An air‐tolerant, simple yet highly efficient copper‐catalyzed methoxylation of (hetero) aryl
bromides and some activated chlorides has been developed by using copper (II) chloride/2 …

Perchlorinated Triptycene Tribenzoquinone

Y Shoji, S Yamamoto, T Fukushima - Chemistry Letters, 2021 - academic.oup.com
Chlorination of triptycene tribenzoquinone 1H using sulfuryl chloride gives new
perchlorinated derivative 1Cl, which exhibits a significantly enhanced electron-accepting …

Through-space or through-bond? The important role of cofaciality in orbital reordering and its implications for hole (de) stabilization in polychromophoric assemblies

MV Ivanov, SH Wadumethrige, D Wang… - The Journal of …, 2017 - ACS Publications
Developing predictive tools for the elucidation of redox and optical properties of
polychromophoric assemblies is crucial for the rational design of efficient charge-transfer …

Synthesis of 1, 2, 5, 6-and 1, 4, 5, 8-anthracenetetrone: Building blocks for π-conjugated small molecules and polymers

F Glöcklhofer, B Stöger, J Fröhlich - Synthetic Communications, 2018 - Taylor & Francis
Reliable reactions for the synthesis of two interesting anthracenetetrones have been
identified and optimized. Both syntheses start from dihydroxy-9, 10-anthraquinones and …