Inorganic synthesis based on reactions of ionic liquids and deep eutectic solvents

T Zhang, T Doert, H Wang, S Zhang… - Angewandte Chemie …, 2021 - Wiley Online Library
Ionic liquids and deep eutectic solvents are of growing interest as solvents for the resource‐
efficient synthesis of inorganic materials. This Review covers chemical reactions of various …

Cobalt deposition from ionothermally dissolved cobalt oxides

J Richter, T Pietsch, M Ruck - ChemSusChem, 2023 - Wiley Online Library
Owing to the environmental problems of numerous metal production processes, there is a
growing need for more energy‐efficient approaches. Cobalt is considered a strategic …

Ionometallurgy: an academic exercise or promising approach?

J Richter, M Ruck - RSC Sustainability, 2024 - pubs.rsc.org
Metals and functional metal-containing compounds are indispensable mass products.
Metals are produced from low-reactive resources that are activated by very high …

Unconventional electrochemical behaviors of Cu underpotential deposition in a chloride-based deep eutectic solvent: high underpotential shift and low coverage

Z Tan, K Li, Y Gu, Z Nan, W Wang, L Sun… - Analytical …, 2023 - ACS Publications
The (5× 5) Moiré pattern resulting from coadsorption of Cu atoms and chloride ions on the
Au (111) electrode is one of the most classical structures for underpotential deposition …

Critical Investigation of Betaine Hydrochloride‐Based Deep Eutectic Solvent for Ionometallurgical Metal Production

J Richter, T Pietsch, N Elsner, M Ruck - ChemistryOpen, 2023 - Wiley Online Library
The applicability of a deep eutectic solvent (DES) consisting of betainium hydrochloride,
urea and glycerol is examined with respect to ionometallurgical metal extraction and …

Synthesis and characterization of divalent metal–betaine–bistriflimide complexes: a property comparison with metal bistriflimide salts

L Guglielmero, L Ciccone, A Mezzetta, F D'Andrea… - Dalton …, 2024 - pubs.rsc.org
A panel of metal–betaine–bistriflimide complexes (with minimum formula M [Bet] 2 [Tf2N] 2,
where M= Mg, Ca, Zn, Cu and Ni) has been prepared in high purity and a quantitative yield …

N-heterocyclic carbene-mediated oxidation of copper (I) in an imidazolium ionic liquid

S Shah, T Pietsch, M Ruck - Zeitschrift für Naturforschung B, 2023 - degruyter.com
The aerobic oxidation of copper (I) to copper (II) was studied in the ionic liquid (IL) 1-n-butyl-
3-methylimidazolium acetate [BMIm][OAc]. Temperatures above 100° C promote the …

Ionothermal Synthesis of Sulfidobismuth spiro‐Dicubane Cations

M Knies, M Ruck - ChemistryOpen, 2022 - Wiley Online Library
Bi2S3 was dissolved in the presence of NaCl in the ionic liquid [BMIm] Cl⋅ 4AlCl3 (BMIm= 1‐
n‐butyl‐3‐methylimidazolium) through annealing the mixture at 180° C. Upon cooling to …

Ionische Flüssigkeiten und stark eutektische Lösungsmittel in der anorganischen Synthese

T Zhang, T Doert, H Wang, S Zhang… - Angewandte …, 2021 - Wiley Online Library
Ionische Flüssigkeiten und stark eutektische Lösungsmittel sind für die ressourceneffiziente
Synthese anorganischer Materialien von zunehmendem Interesse. Dieser Aufsatz …