There have been significant advances in our understanding of mononuclear nonheme iron
oxygenases since our 1996 Chemical Reviews article, 1 promoted in large part by the many …

From an economic perspective, textile and paper bleaching are amongst the most important
oxidation processes. The removal of unwanted chromophores, be it stains on cloths or …

A new paradigm for oxygen activation is required for enzymes such as methane
monooxygenase (MMO), for which catalysis depends on a nonheme diiron center instead of …

Oxoiron (IV) species are often implicated in the catalytic cycles of oxygen-activating non-
heme iron enzymes. The paucity of suitable model complexes stimulated us to fill this void …

Focused electron beam irradiation has been used to create mono and divacancies in
graphene within a defined area, which then act as trap sites for mobile Fe atoms initially …

The catalytic properties of the metal–organic framework Fe2 (dobdc), containing open Fe (II)
sites, include hydroxylation of phenol by pure Fe2 (dobdc) and hydroxylation of ethane by its …

Understanding the mechanisms of dioxygen activation at the metal centers is important for
unraveling the mechanisms of metal-containing oxidases and oxygenases, synthesizing …

We describe mechanistic studies of the soluble methane monooxygenase (sMMO) enzyme
system from Methylococcus capsulatus (Bath). Interactions among the three sMMO …

Higher oxidation state complexes of transition metals become progressively rarer the further
to the right the element is found in the periodic table. For early transition metals the d states …

In recent years, Positron Emission Tomography (PET) has become a practical, high
performance clinical imaging modality for visualization of biological process within the living …