Conspectus Boron heterocycles represent an important subset of heteroatom-incorporated
rings, attracting attention from organic, inorganic, and materials chemists. The empty pz …

Neutral 1-boraphenalene displays the isoelectronic structure of the phenalenyl carbocation
and is expected to behave as an attractive organoboron multi-redox system. However, the …

Systems that possess open-and closed-shell behavior attract significant attention from
researchers due to their inherent redox and charge transport properties. Herein, we report …

The unprecedented silylene-supported dibenzodiboraoxepin 2 and 9, 10-
diboraphenanthrene complexes 6 and 8 were synthesized. The (NHSi) 2B2 …

Molecular topology synthesis of polycyclic aromatic hydrocarbons (PAHs) with diradical
character takes root in intramolecular coupling breakthrough. Herein, we report selective Mn …

Although the activation of elemental sulfur by main group compounds is well-documented in
the literature, the products of such reactions are often heterocyclic in nature. However, the …

Designing molecules that can undergo late-stage modifications resulting in specific optical
properties is useful for developing structure-function trends in materials, which ultimately …

One-electron reduction of diboratriazole 1 with potassium graphite (KC8) generates the
radical anion 1•–• K+, which undergoes a salt (KCl) elimination reaction upon addition of an …

Herein, we report the syntheses and electronic structures of crystalline dianionic as well as
neutral diboron-centered classical diradicaloids as boron analogues of classical Thiele …

Herein, we report the inaugural instance of N‐heterocyclic silylene (NHSi)‐coordinated
copper amide emitters (2–5). These complexes exhibit thermally activated delayed …