Singlet Oxygen Production and Biological Activity of Hexanuclear Chalcocyanide Rhenium Cluster Complexes [{Re6Q8}(CN)6]4– (Q = S, Se, Te)

AO Solovieva, K Kirakci, AA Ivanov, P Kubát… - Inorganic …, 2017 - ACS Publications
Octahedral rhenium cluster complexes have recently emerged as relevant building blocks
for the design of singlet oxygen photosensitizing materials toward biological applications …

[HTML][HTML] Systematic Study of Vibrational Spectra of Octahedral Rhenium Clusters {Re6S8-xBrx}Bry (x = 0, 1, 2, 3, 4) with Mixed Sulfur/Bromine Inner Ligands

AY Ledneva, MN Ivanova, PA Poltarak, SS Yarovoy… - Symmetry, 2023 - mdpi.com
A series of rhenium compounds with the octahedral cluster core {Re6S8-xBrx}(x= 0–4): with
molecular and polymeric structure were obtained. In these compounds the cluster core …

Theoretical ab Initio Study on Cooperativity Effects between Nitro π‐hole and Halogen Bonding Interactions

B Galmés, D Martínez, MF Infante‐Carrió… - …, 2019 - Wiley Online Library
This article analyzes the interplay between nitro's π‐hole and halogen–bonding (XB)
interactions in nitroarenes. Remarkable cooperativity effects are observed when π–hole and …

Soluble molecular rhenium cluster complexes exhibiting multistage terminal ligands reduction

AA Ulantikov, YM Gayfulin, AA Ivanov… - Inorganic …, 2020 - ACS Publications
Substitution of terminal halide ligands of octahedral rhenium cluster complexes [Re6Q8X6] 4–
in a melt of 4, 4′-bipyridine (bpy) led to us obtaining four new compounds with the general …

Use of [Re6Q8 (CN) 6] 4−(Q= S, Se, Te) cluster anions and Cu (I) cationic complexes with 2, 2′-bipyridine for the construction of new cyano-bridged coordination …

AV Ermolaev, AI Smolentsev, YV Mironov - Polyhedron, 2015 - Elsevier
A series of four new coordination compounds [{Cu (bpy) 2 (μ-CN) Cu (bpy)} 2 Re 6 S 8 (CN)
6]· bpy· 2H 2 O (1),[{Cu (bpy)} 2 (μ-CN)][{Cu (bpy)} 3 Re 6 S 8 (CN) 6](2) and [{Cu (bpy)(μ …

First cyano-bridged coordination polymers based on N, N'-chelated Ag (I) ions and octahedral rhenium (III) chalcocyanide clusters exhibiting unusually long-lived …

AV Ermolaev, AI Smolentsev, KA Brylev… - Journal of Molecular …, 2018 - Elsevier
First examples of Ag (I)-containing coordination polymers based on octahedral rhenium (III)
chalcocyanide clusters, namely [{Ag (bpy)}{Ag 4 (bpy) 4 (μ-CN)}{Re 6 Q 8 (CN) 6}](Q= S in 1 …

Facile Substitution of Bridging SO22– Ligands in Re12 Bioctahedral Cluster Complexes

YM Gayfulin, AI Smolentsev, SG Kozlova… - Inorganic …, 2017 - ACS Publications
Selective substitution of μ-SO22–groups by either O2–or Se2–ions occurs upon heating the
bioctahedral rhenium cluster complex K6 [Re12CS14 (μ-SO2) 3 (CN) 6] in air atmosphere or …

Organometallic rhenium (III) chalcogenide clusters: coordination of N-heterocyclic carbenes

JL Durham, WB Wilson, DN Huh, R McDonald… - Chemical …, 2015 - pubs.rsc.org
The preparation of rhenium based octahedral clusters containing N-heterocyclic carbenes is
described. These represent the first examples of [M6 (μ3-Q) 8] n+ or [M6 (μ3-X) 8] n+ clusters …

Synthesis, Structure, and Spectroscopic Study of Redox-Active Heterometallic Cluster-Based Complexes [Re5MoSe8(CN)6]n

VK Muravieva, IP Loginov, TS Sukhikh… - Inorganic …, 2021 - ACS Publications
The heterometallic cluster-based compound K5 [Re5MoSe8 (CN) 6] was obtained by high-
temperature reaction from a mixture of ReSe2 and MoSe2 in molten potassium cyanide. The …

Zero-Magnetic-Field Splitting in the Excited Triplet States of Octahedral Hexanuclear Molybdenum(II) Clusters: [{Mo6X8}(n-C3F7COO)6]2– (X = Cl, Br, or I)

S Akagi, E Sakuda, A Ito… - The Journal of Physical …, 2017 - ACS Publications
Temperature (T)-dependent emission from [{Mo6X8}(n-C3F7COO) 6] 2–(X= Cl (1), Br (2),
and I (3)) in optically transparent polyethylene glycol dimethacrylate matrices were studied …