Alkene hydrosilylation using tertiary silanes with α-diimine nickel catalysts. redox-active ligands promote a distinct mechanistic pathway from platinum catalysts

I Pappas, S Treacy, PJ Chirik - ACS Catalysis, 2016 - ACS Publications
Combination of the readily available α-diimine ligand,((Ar N C (Me)) 2 Ar= 2, 6-iPr2–
C6H3),(iPrDI) with air-stable nickel (II) bis (carboxylates) generated a highly active catalyst …

FI Catalysts: new olefin polymerization catalysts for the creation of value‐added polymers

M Mitani, J Saito, S Ishii, Y Nakayama… - The Chemical …, 2004 - Wiley Online Library
This contribution reports the discovery and application of phenoxy–imine‐based catalysts for
olefin polymerization. Ligand‐oriented catalyst design research has led to the discovery of …

Olefin poly/oligomerizations by metal precatalysts bearing non–heterocyclic N–donor ligands

S Budagumpi, RS Keri, A Biffis, SA Patil - Applied Catalysis A: General, 2017 - Elsevier
The use of transition metal complexes of non–heterocyclic N–donor ligands as olefin
oligo/polymerization precatalysts is reviewed. These metal complexes with definite steric …

Structural and electronic trends for five coordinate 1 st row transition metal complexes: Mn (II) to Zn (II) captured in a bis (iminopyridine) framework

S Ouanounou, WC Shih, TG Ong, GPA Yap… - Dalton …, 2016 - pubs.rsc.org
The preparation and characterization of a series of divalent 3d transition metal complexes
supported by a tridentate planar bis (iminopyridine) ligand are reported. The complexes {2, 6 …

Catalytic behavior of Co (II) complexes with 2‐(benzimidazolyl)‐6‐(1‐(arylimino) ethyl) pyridine ligands on isoprene stereospecific polymerization

G Wang, X Jiang, W Zhao, WH Sun… - Journal of Applied …, 2014 - Wiley Online Library
Polymerization behaviors of isoprene under different polymerization conditions with 2‐(1‐
methyl‐2‐benzimidazolyl)‐6‐(1‐(arylimino) ethyl) pyridine cobalt (II) dichloride and …

Facile Syntheses of Bis[1-(arylimino)ethyl]pyridine−MoCl3/MMAO Catalytic Systems and Their Dual Catalytic Functions for ROMP of Norbornene and Linear …

K Hiya, Y Nakayama, H Yasuda - Macromolecules, 2003 - ACS Publications
ROMP (ring-opening metathesis polymerization) of norbornene using a series of 2, 6-bis [1-
(arylimino) ethyl] pyridine− MoCl3/cocatalyst systems was explored, and the 2, 6-bis [1-(2, 6 …

Pitfalls and Bias: Entry testing and the overrepresentation of Romani children in special education.

J White - 2012 - urresearch.rochester.edu
This policy paper examines many of the ways in which Romani children from Central and
South Eastern Europe are segregated from their non-Romani peers and placed in special …

Parallel solid-phase synthesis, screening, and encoding strategies for olefin-polymerization catalysts

TR Boussie, V Murphy, KA Hall, C Coutard, C Dales… - Tetrahedron, 1999 - Elsevier
A solid-phase protocol has been developed that allows for the parallel synthesis, screening,
and chemical encoding of nickel (II) and palladium (II) olefin-polymerization catalysts. These …

Polymerization Catalysts with dn Electrons (n = 1−4):  A Theoretical Study

R Schmid, T Ziegler - Organometallics, 2000 - ACS Publications
We present an investigation on the potential of first-row transition metals with a d-electron
count from 1 to 4 as olefin polymerization catalysts by means of first-principles density …

Selective isomerization and linear dimerization of olefins using cobalt catalysts

BL Small - US Patent 7,001,964, 2006 - Google Patents
Provided herein is an oligomerization product formed from alpha-olefins having at least
three carbon atoms comprising dimers, at least about 80 weight percent of which are linear …