Upcycling to sustainably reuse plastics
Plastics are now indispensable in daily lives. However, the pollution from plastics is also
increasingly becoming a serious environmental issue. Recent years have seen more …
increasingly becoming a serious environmental issue. Recent years have seen more …
Oxygen reduction by homogeneous molecular catalysts and electrocatalysts
ML Pegis, CF Wise, DJ Martin, JM Mayer - Chemical Reviews, 2018 - ACS Publications
The oxygen reduction reaction (ORR) is a key component of biological processes and
energy technologies. This Review provides a comprehensive report of soluble molecular …
energy technologies. This Review provides a comprehensive report of soluble molecular …
Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites
Enzymatic haem and non-haem high-valent iron–oxo species are known to activate strong C–
H bonds, yet duplicating this reactivity in a synthetic system remains a formidable challenge …
H bonds, yet duplicating this reactivity in a synthetic system remains a formidable challenge …
Proton-coupled electron transfer
DR Weinberg, CJ Gagliardi, JF Hull, CF Murphy… - Chemical …, 2012 - ACS Publications
An initial review (PCET1) on proton-coupled electron transfer (PCET) by Huynh and Meyer
appeared in Chemical Reviews in 2007.(1) This is a follow-up on the original. It was …
appeared in Chemical Reviews in 2007.(1) This is a follow-up on the original. It was …
Proton-coupled electron transfer
MHV Huynh, TJ Meyer - Chemical Reviews, 2007 - ACS Publications
At the core of many important energy conversion processes in chemistry and biology are
oxidation-reduction reactions in which both electrons and protons are transferred. An …
oxidation-reduction reactions in which both electrons and protons are transferred. An …
What drives radical halogenation versus hydroxylation in mononuclear nonheme iron complexes? A combined experimental and computational study
Nonheme iron halogenases are unique enzymes in nature that selectively activate an
aliphatic C–H bond of a substrate to convert it into C–X (X= Cl/Br, but not F/I). It is proposed …
aliphatic C–H bond of a substrate to convert it into C–X (X= Cl/Br, but not F/I). It is proposed …
Selective photocatalytic C–C bond cleavage under ambient conditions with earth abundant vanadium complexes
Selective C–C bond cleavage under ambient conditions is a challenging chemical
transformation that can be a valuable tool for organic syntheses and macromolecular …
transformation that can be a valuable tool for organic syntheses and macromolecular …
A high-spin iron (IV)–oxo complex supported by a trigonal nonheme pyrrolide platform
JP Bigi, WH Harman, B Lassalle-Kaiser… - Journal of the …, 2012 - ACS Publications
We report the generation and characterization of a new high-spin iron (IV)–oxo complex
supported by a trigonal nonheme pyrrolide platform. Oxygen-atom transfer to [(tpaMes) …
supported by a trigonal nonheme pyrrolide platform. Oxygen-atom transfer to [(tpaMes) …
The crystal structure of a high-spin oxoiron (IV) complex and characterization of its self-decay pathway
J England, Y Guo, ER Farquhar… - Journal of the …, 2010 - ACS Publications
[FeIV (O)(TMG3tren)] 2+(1; TMG3tren= 1, 1, 1-tris {2-[N 2-(1, 1, 3, 3-tetramethylguanidino)]
ethyl} amine) is a unique example of an isolable synthetic S= 2 oxoiron (IV) complex, which …
ethyl} amine) is a unique example of an isolable synthetic S= 2 oxoiron (IV) complex, which …
A non-heme diiron complex for (electro) catalytic reduction of dioxygen: tuning the selectivity through electron delivery
L Wang, M Gennari, FG Cantú Reinhard… - Journal of the …, 2019 - ACS Publications
In the oxygen reduction reaction (ORR) domain, the investigation of new homogeneous
catalysts is a crucial step toward the full comprehension of the key structural and/or …
catalysts is a crucial step toward the full comprehension of the key structural and/or …