Conspectus Benzo-fused skeletons are ubiquitous in agrochemicals, medicines, natural
products, catalysts, and other organic function materials. The assembly of these skeletons in …

The Catellani reaction is known as a powerful strategy for the expeditious synthesis of highly
substituted arenes and benzo‐fused rings, which are usually difficult to access through …

Methods that can simultaneously install multiple different functional groups to heteroarenes
via C− H functionalizations are valuable for complex molecule synthesis, which, however …

In this work, we describe a Catellani-type C–H glycosylation to provide rapid access to
various highly decorated α-C-(hetero) aryl glycosides in a modular and stereoselective …

Palladium/norbornene (Pd/NBE) cooperative catalysis has received enormous attention and
found numerous synthetic applications in the past two decades. Considering the critical …

C–N axially chiral skeletons are ubiquitous in bioactive natural products, pharmaceuticals,
and chiral ligands. However, their atroposelective synthesis remains a formidable challenge …

All-carbon tetrasubstituted olefins have been found in numerous biologically important
compounds and organic materials. However, regio-and stereocontrolled construction of this …

Due to the dichotomy between reactivity and stereoselectivity, the synthesis of axially chiral
biaryls via enantioselective C–H arylation remains a daunting challenge. This full account …

The Catellani reaction is a palladium-catalyzed hydrocarbon-activated multicomponent
tandem reaction involving an aryl halide, an electrophilic coupling reagent and a terminating …

We report a dual-tasked methylation that is based on cooperative palladium/norbornene
catalysis. Readily available (hetero) aryl halides (39 iodides and 4 bromides) and …