A review of the structure, and fundamental mechanisms and kinetics of the leaching of chalcopyrite

Y Li, N Kawashima, J Li, AP Chandra… - Advances in colloid and …, 2013 - Elsevier
Most investigators regard CuFeS 2 as having the formal oxidation states of Cu+ Fe 3+(S 2−)
2. However, the spectroscopic characterisation of chalcopyrite is clearly influenced by the …

The dissolution and passivation mechanism of chalcopyrite in bioleaching: An overview

H Zhao, Y Zhang, X Zhang, L Qian, M Sun, Y Yang… - Minerals …, 2019 - Elsevier
Chalcopyrite (CuFeS 2) is the most abundant copper-containing resource in the earth and is
also widely distributed in solid wastes and secondary resources. Biohydrometallurgy …

The effects of hydroxyl on selective separation of chalcopyrite from pyrite: A mechanism study

H Zhang, F Zhang, W Sun, D Chen, J Chen… - Applied Surface …, 2023 - Elsevier
The separation of chalcopyrite from pyrite is usually carried out under high alkaline
conditions. However, the separation mechanism of chalcopyrite from pyrite under high …

Chalcopyrite hydrometallurgy at atmospheric pressure: 1. Review of acidic sulfate, sulfate–chloride and sulfate–nitrate process options

HR Watling - Hydrometallurgy, 2013 - Elsevier
The need to process low-grade and/or complex chalcopyrite-containing ores that cannot be
concentrated is the main driver for the development of hydrometallurgical processes. The …

Adsorption mechanisms and effects of thiocarbamate collectors in the separation of chalcopyrite from pyrite minerals: DFT and experimental studies

PP Mkhonto, X Zhang, L Lu, W Xiong, Y Zhu, L Han… - Minerals …, 2022 - Elsevier
We employed computational density functional theory (DFT) and microflotation tests
complemented by analysis of electronic properties and X-ray photoelectron spectroscopy …

Effects of redox potential on chalcopyrite leaching: An overview

Z Tian, H Li, Q Wei, W Qin, C Yang - Minerals Engineering, 2021 - Elsevier
Chalcopyrite is a prime, plentiful and widely distributed form of copper-bearing mineral.
Compared with the traditional pyrometallurgy process, biohydrometallurgy has …

Dissolution and passivation mechanisms of chalcopyrite during bioleaching: DFT calculation, XPS and electrochemistry analysis

J Wang, X Gan, H Zhao, M Hu, K Li, W Qin, G Qiu - Minerals Engineering, 2016 - Elsevier
In this work, density functional theory (DFT) calculation, X-ray photoelectron spectroscopy
(XPS) and electrochemistry analysis were carried out to investigate the dissolution process …

Flotation separation of molybdenite from chalcopyrite using rhodanine-3-acetic acid as a novel and effective depressant

C Wang, R Liu, M Wu, Z Xu, M Tian, Z Yin, W Sun… - Minerals …, 2021 - Elsevier
The selective separation of molybdenite from chalcopyrite is difficult because of their similar
floatability in the presence of a collector. In this study, rhodanine-3-acetic acid (3-Rd) was …

Heterogeneous activation of peroxymonocarbonate by chalcopyrite (CuFeS2) for efficient degradation of 2, 4-dichlorophenol in simulated groundwater

X Xu, D Tang, J Cai, B Xi, Y Zhang, L Pi… - Applied Catalysis B …, 2019 - Elsevier
Recently, increasing attention has been paid to the activated peroxymonocarbonate (APMC)
process, because it is envisioned to be engineered for the chemical oxidation remediation of …

Effects of surface spatial structures and electronic properties of chalcopyrite and pyrite on Z-200 selectivity

J Chen, J Wang, Y Li, M Liu, Y Liu, C Zhao, W Cui - Minerals Engineering, 2021 - Elsevier
Chalcopyrite (CuFeS 2) is one of the main copper minerals, and is always found associated
with pyrite (FeS 2). To obtain a satisfactory Cu concentration, the undesirable pyrite …