Non-universal features in uniaxially extensional rheology of linear polymer melts and concentrated solutions: A review

Y Matsumiya, H Watanabe - Progress in Polymer Science, 2021 - Elsevier
Rheological behavior of polymeric liquids has been considered to be universally determined
by a few time-independent molecular parameters (such as the Rouse relaxation time and …

A review of the second normal-stress difference; its importance in various flows, measurement techniques, results for various complex fluids and theoretical predictions

O Maklad, RJ Poole - Journal of Non-Newtonian Fluid Mechanics, 2021 - Elsevier
Shear flow is ubiquitous. Not only is it arguably the most widely-used deformation type to
characterise complex fluids in rheological studies but also, in practice, the deformation most …

Advances and new opportunities in the rheology of physically and chemically reversible polymers

S Wu, Q Chen - Macromolecules, 2021 - ACS Publications
The advances in understanding the dynamics of both the physically and chemically
reversible networks are summarized from a rheological perspective. The focus is placed on …

Nonlinear shear rheology of entangled polymer rings

D Parisi, S Costanzo, Y Jeong, J Ahn, T Chang… - …, 2021 - ACS Publications
Steady-state shear viscosity η (γ̇) of unconcatenated ring polymer melts as a function of the
shear rate γ̇ is studied by a combination of experiments, simulations, and theory …

When polymer chains are highly aligned: a perspective on extensional rheology

Q Huang - Macromolecules, 2022 - ACS Publications
We provide a Perspective on recent findings in extensional rheology for polymer melts and
solutions with different macromolecular architectures. For linear polymer systems, we focus …

Linear and nonlinear viscoelasticities of dissociative and associative covalent adaptable networks: discrepancies and limits

X Cui, N Jiang, J Shao, H Zhang, Y Yang… - Macromolecules, 2023 - ACS Publications
Covalent adaptable networks (CANs) can be classified into dissociative (Diss-CANs) and
associative (Asso-CANs) networks according to the exchange mechanism of covalent …

Nature of steady-state fast flow in entangled polymer melts: chain stretching, shear thinning, and viscosity scaling

Z Xu, R Sun, W Lu, S Patil, J Mays, KS Schweizer… - …, 2022 - ACS Publications
Understanding the nonequilibrium dynamics of topologically entangled polymers under
strong external deformation has been a grand challenge in polymer science for more than …

Rheological properties of sodium alginate solutions in the presence of added salt: An application of Kulicke equation

A Dodero, S Vicini, M Alloisio, M Castellano - Rheologica Acta, 2020 - Springer
Mark–Houwink parameters are determined for sodium alginate with low (SA LV) and
medium (SA MV) molecular mass via a rheological approach. Firstly, salt screening …

Threading–unthreading transition of linear-ring polymer blends in extensional flow

A Borger, W Wang, TC O'Connor, T Ge… - ACS Macro …, 2020 - ACS Publications
Adding small amounts of ring polymers to a matrix of their linear counterparts is known to
increase the zero-shear-rate viscosity because of linear-ring threading. Uniaxial extensional …

Flexibility, extensibility, and ratio of Kuhn length to packing length govern the pinching dynamics, coil-stretch transition, and rheology of polymer solutions

J Dinic, V Sharma - Macromolecules, 2020 - ACS Publications
We elucidate the influence of chemical structure on macromolecular hydrodynamics,
rheological response, and pinching dynamics underlying drop formation/liquid transfer using …